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Aqua-(picolinato N-oxide-?O,O)(pyridine-2,6-dicarboxyl-ato-?O,N,O')iron(III) monohydrate.

ABSTRACT: In the title compound, [Fe(C(6)H(4)NO(3))(C(7)H(3)NO(4))(H(2)O)]·H(2)O, the Fe(III) ion is coordinated by two O and one N atoms from a pyridine-2,6-dicarboxyl-ate ligand, by two O atoms from a picolinate N-oxide ligand and by one water O atom in a distorted octa-hedral geometry [Fe-O = 1.940?(3)-2.033?(3)?Å and Fe-N = 2.057?(4)?Å]. In the crystal structure, the coordinated and solvent water mol-ecules contribute to the formation of O-H?O hydrogen bonds, which link the mol-ecules into layers parallel to the ab plane.

SUBMITTER: Han D

PROVIDER: S-EPMC2959446 | biostudies-other | 2008

REPOSITORIES: biostudies-other

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Aqua-(picolinato N-oxide-κO,O)(pyridine-2,6-dicarboxyl-ato-κO,N,O')iron(III) monohydrate.

Han Dongdong D Wang Dong'e D

Acta crystallographica. Section E, Structure reports online 20080927 Pt 10

In the title compound, [Fe(C(6)H(4)NO(3))(C(7)H(3)NO(4))(H(2)O)]·H(2)O, the Fe(III) ion is coordinated by two O and one N atoms from a pyridine-2,6-dicarboxyl-ate ligand, by two O atoms from a picolinate N-oxide ligand and by one water O atom in a distorted octa-hedral geometry [Fe-O = 1.940 (3)-2.033 (3) Å and Fe-N = 2.057 (4) Å]. In the crystal structure, the coordinated and solvent water mol-ecules contribute to the formation of O-H⋯O hydrogen bonds, which link the mol-ecules into layers para ...[more]

PMID: 21201074

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Di-?-hydroxido-bis-[aqua-(pyridine-2,6-dicarboxyl-ato)iron(III)] monohydrate.

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