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A new monoclinic polymorph of trans-dichloridodipyridine-palladium(II).

ABSTRACT: In the structure of the title compound, [PdCl(2)(C(5)H(5)N)(2)], the Pd(II) atom is located on an inversion centre and the pyridine rings are coplanar. There is inter-molecular ?-? stacking between the pyridyl rings, with a centroid-to-centroid separation of 3.916?(1)?Å. The structure is a new polymorph of two previously determined structures [Viossat, Dung & Robert (1993 ?). Acta Cryst. C49, 84-85; Liao & Lee (2006 ?). Acta Cryst. E62, m680-m681].

SUBMITTER: Lee HM

PROVIDER: S-EPMC2959498 | biostudies-other | 2008

REPOSITORIES: biostudies-other

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A new monoclinic polymorph of trans-dichloridodipyridine-palladium(II).

Lee Hon Man HM Liao Chuang-Yi CY

Acta crystallographica. Section E, Structure reports online 20081022 Pt 11

In the structure of the title compound, [PdCl(2)(C(5)H(5)N)(2)], the Pd(II) atom is located on an inversion centre and the pyridine rings are coplanar. There is inter-molecular π-π stacking between the pyridyl rings, with a centroid-to-centroid separation of 3.916 (1) Å. The structure is a new polymorph of two previously determined structures [Viossat, Dung & Robert (1993 ▶). Acta Cryst. C49, 84-85; Liao & Lee (2006 ▶). Acta Cryst. E62, m680-m681]. ...[more]

PMID: 21580886

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