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3-Phenyl-1-[2-(3-phenyl-isoquinolin-1-yl)-diselan-yl]isoquinoline.

ABSTRACT: The complete molecule of the title compound, C(30)H(20)N(2)Se(2), is generated by a crystallographic inversion centre at the mid-point of the Se-Se bond. The dihedral angle between the isoquinoline-1-selenol group and the phenyl ring is 14.92?(2)°. The herringbone-like packing of the structure is supported by inter-molecular ?-? stacking inter-actions with a shortest perpendicular distance between isoquinoline groups of 3.514?Å; the slippage between these ring systems is 0.972?Å, and the distance between the centroids of the six-membered carbon rings is 3.645?(3)?Å.

SUBMITTER: Hathwar VR

PROVIDER: S-EPMC2959858 | biostudies-other | 2008

REPOSITORIES: biostudies-other

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3-Phenyl-1-[2-(3-phenyl-isoquinolin-1-yl)-diselan-yl]isoquinoline.

Hathwar Venkatesha R VR Prabakaran K K Subashini R R Manivel P P Khan F Nawaz FN

Acta crystallographica. Section E, Structure reports online 20081108 Pt 12

The complete molecule of the title compound, C(30)H(20)N(2)Se(2), is generated by a crystallographic inversion centre at the mid-point of the Se-Se bond. The dihedral angle between the isoquinoline-1-selenol group and the phenyl ring is 14.92 (2)°. The herringbone-like packing of the structure is supported by inter-molecular π-π stacking inter-actions with a shortest perpendicular distance between isoquinoline groups of 3.514 Å; the slippage between these ring systems is 0.972 Å, and the distanc ...[more]

PMID: 21581273

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