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2,2'-(Butane-1,4-di-yl)diisoquinolinium tetra-chloridozincate(II).

ABSTRACT: The crystal of the title compound, (C(22)H(22)N(2))[ZnCl(4)], consists of 2,2'-(butane-1,4-di-yl)diisoquinolinium organic cations and [ZnCl(4)](2-) complex anions. The cation is located across a twofold axis and the Zn(II) atom of the anion is located on the other twofold axis. The centroid-centroid distance between parallel pyridine rings of neighboring mol-ecules is 3.699?(3)?Å, but the face-to-face separation of 3.601?(3)?Å suggests there is no significant ?-? stacking in the crystal structure.

SUBMITTER: Fan ZF 

PROVIDER: S-EPMC2959863 | biostudies-other | 2008

REPOSITORIES: biostudies-other

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2,2'-(Butane-1,4-di-yl)diisoquinolinium tetra-chloridozincate(II).

Fan Zhi-Fang ZF   Xiao Xin X   Zhang Yun-Qian YQ   Xue Sai-Feng SF   Tao Zhu Z  

Acta crystallographica. Section E, Structure reports online 20081126 Pt 12

The crystal of the title compound, (C(22)H(22)N(2))[ZnCl(4)], consists of 2,2'-(butane-1,4-di-yl)diisoquinolinium organic cations and [ZnCl(4)](2-) complex anions. The cation is located across a twofold axis and the Zn(II) atom of the anion is located on the other twofold axis. The centroid-centroid distance between parallel pyridine rings of neighboring mol-ecules is 3.699 (3) Å, but the face-to-face separation of 3.601 (3) Å suggests there is no significant π-π stacking in the crystal structur  ...[more]