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[O-Ethyl N-(4-nitro-phen-yl)thio-carbam-ato-?S](tri-p-tolyl-phosphine-?P)gold(I).

ABSTRACT: A nearly linear coordination geometry for Au is found in the title compound, [Au(C(9)H(9)N(2)O(3)S)(C(21)H(21)P)]. The thio-carbamate ligand is orientated so that the aryl group is in close proximity to the Au atom, consistent with an Au?? contact [Au?Cg = 3.351?(5)?Å; Cg is the centroid of the aromatic ring].

SUBMITTER: Broker GA 

PROVIDER: S-EPMC2959883 | biostudies-other | 2008

REPOSITORIES: biostudies-other

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[O-Ethyl N-(4-nitro-phen-yl)thio-carbam-ato-κS](tri-p-tolyl-phosphine-κP)gold(I).

Broker Grant A GA   Tiekink Edward R T ER  

Acta crystallographica. Section E, Structure reports online 20081120 Pt 12

A nearly linear coordination geometry for Au is found in the title compound, [Au(C(9)H(9)N(2)O(3)S)(C(21)H(21)P)]. The thio-carbamate ligand is orientated so that the aryl group is in close proximity to the Au atom, consistent with an Au⋯π contact [Au⋯Cg = 3.351 (5) Å; Cg is the centroid of the aromatic ring]. ...[more]