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(?-Penta-methyl-cyclo-penta-dien-yl)(?-p-toluene-sulfonamide)ruthenium(II) tetra-phenyl-borate.

ABSTRACT: The crystal structure of the title compound, [Ru(C(10)H(15))(C(7)H(9)NO(2)S)]C(24)H(20)B, has been determined as part of our investigation into the structural and biological properties of organometallic Ru(II)-arene-Cp* complex salts of the type [R-PhRuCp*](+)·X(-) (where Cp* is penta-methyl-cyclo-penta-diene). Tethering the RuCp* group to the benzene ring of p-toluene-sulfonamide results in only minor changes to the mol-ecular geometry of the sulfonamide, but, together with crystallization as the [BPh(4)](-) salt, effectively blocks involvement of the sulfonamide group in N-H?O hydrogen-bonding networks.

SUBMITTER: Loughrey BT 

PROVIDER: S-EPMC2960125 | biostudies-other | 2008

REPOSITORIES: biostudies-other

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(η-Penta-methyl-cyclo-penta-dien-yl)(η-p-toluene-sulfonamide)ruthenium(II) tetra-phenyl-borate.

Loughrey Bradley T BT   Williams Michael L ML   Poulsen Sally-Ann SA   Healy Peter C PC  

Acta crystallographica. Section E, Structure reports online 20081120 Pt 12

The crystal structure of the title compound, [Ru(C(10)H(15))(C(7)H(9)NO(2)S)]C(24)H(20)B, has been determined as part of our investigation into the structural and biological properties of organometallic Ru(II)-arene-Cp* complex salts of the type [R-PhRuCp*](+)·X(-) (where Cp* is penta-methyl-cyclo-penta-diene). Tethering the RuCp* group to the benzene ring of p-toluene-sulfonamide results in only minor changes to the mol-ecular geometry of the sulfonamide, but, together with crystallization as t  ...[more]