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Three-centre hydrogen bonds in triphenyl-phosphine oxide-hydro-quinone (1/1).

ABSTRACT: The title cocrystal, C(18)H(15)OP·C(6)H(6)O(2), belongs to a series of mol-ecular systems based on triphenyl-phosphine P-oxide. The O atom of the oxide group acts as an acceptor for hydrogen bonds from OH groups of two hydro-quinone mol-ecules which lie on inversion centres [O?O = 2.7451?(17) and 2.681?(2)?Å]. The crystal structure is stabilized by weak C-H?O hydrogen bonds, forming a C(2) (1)(8) chain which runs parallel to the [100] direction.

SUBMITTER: Moreno-Fuquen R

PROVIDER: S-EPMC2960326 | biostudies-other | 2008 Jan

REPOSITORIES: biostudies-other

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Three-centre hydrogen bonds in triphenyl-phosphine oxide-hydro-quinone (1/1).

Moreno-Fuquen Rodolfo R Valderrama-N Jaime J Shankland Kenneth K Fabbiani Francesa P A FP Markvardsen Anders J AJ

Acta crystallographica. Section E, Structure reports online 20080104 Pt 2

The title cocrystal, C(18)H(15)OP·C(6)H(6)O(2), belongs to a series of mol-ecular systems based on triphenyl-phosphine P-oxide. The O atom of the oxide group acts as an acceptor for hydrogen bonds from OH groups of two hydro-quinone mol-ecules which lie on inversion centres [O⋯O = 2.7451 (17) and 2.681 (2) Å]. The crystal structure is stabilized by weak C-H⋯O hydrogen bonds, forming a C(2) (1)(8) chain which runs parallel to the [100] direction. ...[more]

PMID: 21201399

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