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{?-N,N'-Bis[(E)-4-pyridylmethyl-idene]naphthalene-1,5-diamine}bis-[dichlorido(dimethyl sulfide)platinum(II)].

ABSTRACT: The title dinuclear platinum compound, [Pt(2)Cl(4)(C(22)H(16)N(4))(C(2)H(6)S)(2)], with a long bridging bipyridyl-type ligand, is centrosymmetric and the Pt(II) cation shows a slightly distorted square-planar coordination geometry. The Cl ligands are trans to each other, with a Cl-Pt-Cl angle of 178.83?(8)°. The pyridine ring forms a dihedral angle of 48.8?(2)° with the planar PtCl(2)SN unit. Within the mol-ecule, the distance between Pt atoms is 20.262?(5)?Å and the N?N separation between the terminal pyridyl rings is 16.23?(1)Å.

SUBMITTER: Huh HS 

PROVIDER: S-EPMC2960488 | biostudies-other | 2008

REPOSITORIES: biostudies-other

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{μ-N,N'-Bis[(E)-4-pyridylmethyl-idene]naphthalene-1,5-diamine}bis-[dichlorido(dimethyl sulfide)platinum(II)].

Huh Hyun Sue HS   Lee Soon W SW  

Acta crystallographica. Section E, Structure reports online 20080809 Pt 9

The title dinuclear platinum compound, [Pt(2)Cl(4)(C(22)H(16)N(4))(C(2)H(6)S)(2)], with a long bridging bipyridyl-type ligand, is centrosymmetric and the Pt(II) cation shows a slightly distorted square-planar coordination geometry. The Cl ligands are trans to each other, with a Cl-Pt-Cl angle of 178.83 (8)°. The pyridine ring forms a dihedral angle of 48.8 (2)° with the planar PtCl(2)SN unit. Within the mol-ecule, the distance between Pt atoms is 20.262 (5) Å and the N⋯N separation between the t  ...[more]