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A quaternary germanium(II) phosphate, Na[Ge(4)(PO(4))(3)].


ABSTRACT: A new germanium(II) phosphate, sodium tetra-germanium tris-(phosphate), Na[Ge(4)(PO(4))(3)], has been synthesized by a solid-state reaction. The compound is isotypic with A[Sn(4)(PO(4))(3)] (A = Na, K, NH(4)). It features a [Ge(4)(PO(4))(3)](-) framework made up of GeO(3) pyramids and PO(4) tetra-hedra, which are linked by shared corners, yielding a three-dimensional structure. The crystal studied showed partial inversion twinning.

SUBMITTER: Lee CS 

PROVIDER: S-EPMC2960825 | biostudies-other | 2008

REPOSITORIES: biostudies-other

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A quaternary germanium(II) phosphate, Na[Ge(4)(PO(4))(3)].

Lee Chi-Shen CS   Weng Sheng-Feng SF  

Acta crystallographica. Section E, Structure reports online 20080206 Pt 3


A new germanium(II) phosphate, sodium tetra-germanium tris-(phosphate), Na[Ge(4)(PO(4))(3)], has been synthesized by a solid-state reaction. The compound is isotypic with A[Sn(4)(PO(4))(3)] (A = Na, K, NH(4)). It features a [Ge(4)(PO(4))(3)](-) framework made up of GeO(3) pyramids and PO(4) tetra-hedra, which are linked by shared corners, yielding a three-dimensional structure. The crystal studied showed partial inversion twinning. ...[more]

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