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Diaqua-bis(4-formyl-benzoato-?O)zinc(II).

ABSTRACT: The Zn(II) atom in the title compound, [Zn(C(8)H(5)O(3))(2)(H(2)O)(2)], which lies on a twofold rotation axis, is coordinated by two monodentate carboxyl-ate groups and two water mol-ecules in a tetra-hedral geometry; the geometry is distorted towards octa-hedral owing to two long Zn?O(carbon-yl) contacts [2.512?(2)?Å]. Hydrogen-bonding inter-actions give rise to a three-dimensional network. The formyl group is disordered approximately equally over two positions.

SUBMITTER: Deng ZP

PROVIDER: S-EPMC2960827 | biostudies-other | 2008

REPOSITORIES: biostudies-other

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Diaqua-bis(4-formyl-benzoato-κO)zinc(II).

Deng Zhao-Peng ZP Gao Shan S Huo Li-Hua LH Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20080206 Pt 3

The Zn(II) atom in the title compound, [Zn(C(8)H(5)O(3))(2)(H(2)O)(2)], which lies on a twofold rotation axis, is coordinated by two monodentate carboxyl-ate groups and two water mol-ecules in a tetra-hedral geometry; the geometry is distorted towards octa-hedral owing to two long Zn⋯O(carbon-yl) contacts [2.512 (2) Å]. Hydrogen-bonding inter-actions give rise to a three-dimensional network. The formyl group is disordered approximately equally over two positions. ...[more]

PMID: 21201845

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