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Diacetato[N,N'-bis-(2-pyridylmethyl-idene)cyclo-hexane-1,2-diamine]manganese(II) hexa-hydrate.

ABSTRACT: The asymmetric unit of the title compound, [Mn(C(2)H(3)O(2))(2)(C(18)H(20)N(4))]·6H(2)O, consists of a neutral Mn(II) complex with six solvent water mol-ecules. In the complex, the Mn(2+) ion is eight-coordinated in a distorted square-anti-prismatic environment by four N atoms from the tetra-dentate ligand N,N'-bis-(2-pyridylmethyl-idene)cyclo-hexane-1,2-diamine (bpic) and four O atoms from two acetate ligands. The compound displays inter-molecular O-H?O hydrogen-bond inter-actions to form various kinds of ring structures and cyclic water clusters.

SUBMITTER: Hwang IC

PROVIDER: S-EPMC2960837 | biostudies-other | 2008

REPOSITORIES: biostudies-other

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Diacetato[N,N'-bis-(2-pyridylmethyl-idene)cyclo-hexane-1,2-diamine]manganese(II) hexa-hydrate.

Hwang In-Chul IC Ha Kwang K

Acta crystallographica. Section E, Structure reports online 20080206 Pt 3

The asymmetric unit of the title compound, [Mn(C(2)H(3)O(2))(2)(C(18)H(20)N(4))]·6H(2)O, consists of a neutral Mn(II) complex with six solvent water mol-ecules. In the complex, the Mn(2+) ion is eight-coordinated in a distorted square-anti-prismatic environment by four N atoms from the tetra-dentate ligand N,N'-bis-(2-pyridylmethyl-idene)cyclo-hexane-1,2-diamine (bpic) and four O atoms from two acetate ligands. The compound displays inter-molecular O-H⋯O hydrogen-bond inter-actions to form vario ...[more]

PMID: 21201849

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