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Tetra-potassium cis-dioxido-trans-bis-(sulfato-?O)sulfato(?O,O')molybdate(VI).

ABSTRACT: The title compound, K(4)[Mo(VI)O(2)(SO(4))(3)], was precipitated from a melt of molybdenum(VI) oxide and potassium sulfate in potassium disulfate. The compound contains monomeric [Mo(VI)O(2)(SO(4))(3)](4-) anions, with the Mo(VI) atom, both oxide ligands, and the S atom and both ligating O atoms of the bidentate sulfate group lying on a crystallographic mirror plane. One of the potassium cations is nine-coordinate, while the other is eight-coordinate.

SUBMITTER: Schaffer SJ

PROVIDER: S-EPMC2960843 | biostudies-other | 2008

REPOSITORIES: biostudies-other

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Tetra-potassium cis-dioxido-trans-bis-(sulfato-κO)sulfato(κO,O')molybdate(VI).

Schäffer Susan J Cline SJ Berg Rolf W RW

Acta crystallographica. Section E, Structure reports online 20080213 Pt 3

The title compound, K(4)[Mo(VI)O(2)(SO(4))(3)], was precipitated from a melt of molybdenum(VI) oxide and potassium sulfate in potassium disulfate. The compound contains monomeric [Mo(VI)O(2)(SO(4))(3)](4-) anions, with the Mo(VI) atom, both oxide ligands, and the S atom and both ligating O atoms of the bidentate sulfate group lying on a crystallographic mirror plane. One of the potassium cations is nine-coordinate, while the other is eight-coordinate. ...[more]

PMID: 21201837

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