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{N,N-Bis[2-(trimethyl-silylamino)eth-yl]-N'-(trimethyl-silyl)ethane-1,2-diamin-ato(3-)-?N}methyl-zirconium(IV).

ABSTRACT: The title compound, [Zr(CH(3))(C(15)H(39)N(4)Si(3))], is a unique example of a triamido-amine-supported zirconium-methyl complex that crystallized as a monomer with trigonal-bipyramidal geometry at zirconium, featuring a Zr-C bond of 2.2963?(16)?Å.

SUBMITTER: Macmillan SN 

PROVIDER: S-EPMC2960865 | biostudies-other | 2008 Feb

REPOSITORIES: biostudies-other

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{N,N-Bis[2-(trimethyl-silylamino)eth-yl]-N'-(trimethyl-silyl)ethane-1,2-diamin-ato(3-)-κN}methyl-zirconium(IV).

Macmillan Samantha N SN   Tanski Joseph M JM   Waterman Rory R  

Acta crystallographica. Section E, Structure reports online 20080215 Pt 3

The title compound, [Zr(CH(3))(C(15)H(39)N(4)Si(3))], is a unique example of a triamido-amine-supported zirconium-methyl complex that crystallized as a monomer with trigonal-bipyramidal geometry at zirconium, featuring a Zr-C bond of 2.2963 (16) Å. ...[more]