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Bis[1,3-bis-(diphenyl-phosphino)propane-?P:P']silver(I) bis-(chloro-difluoro-acetato-?O)triphenyl-stannate(IV).

ABSTRACT: In the title salt, [Ag(C(27)H(26)P(2))(2)][Sn(C(6)H(5))(3)(C(2)ClF(2)O(2))], the Ag(I) atom exists in a tetra-hedral coordination geometry formed by four P atoms [Ag-P = 2.460?(1)-2.501?(1)?Å], whereas the Sn(IV) atom exists in a trans-trigonal-bipyramidal coordination geometry formed by two O [Sn-O = 2.208?(3) and 2.233?(3)?Å] and three C atoms [Sn-C = 2.115?(4)-2.128?(4)?Å;(? C-Sn-C)= 360.0?(6)°].

SUBMITTER: Teo YY

PROVIDER: S-EPMC2961205 | biostudies-other | 2008

REPOSITORIES: biostudies-other

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Bis[1,3-bis-(diphenyl-phosphino)propane-κP:P']silver(I) bis-(chloro-difluoro-acetato-κO)triphenyl-stannate(IV).

Teo Yin Yin YY Lo Kong Mun KM Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20080423 Pt 5

In the title salt, [Ag(C(27)H(26)P(2))(2)][Sn(C(6)H(5))(3)(C(2)ClF(2)O(2))], the Ag(I) atom exists in a tetra-hedral coordination geometry formed by four P atoms [Ag-P = 2.460 (1)-2.501 (1) Å], whereas the Sn(IV) atom exists in a trans-trigonal-bipyramidal coordination geometry formed by two O [Sn-O = 2.208 (3) and 2.233 (3) Å] and three C atoms [Sn-C = 2.115 (4)-2.128 (4) Å;(Σ C-Sn-C)= 360.0 (6)°]. ...[more]

PMID: 21202235

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