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(2R,3S)-2-Ammonio-3-hydr-oxy-3-(4-nitro-phen-yl)propanoic acid chloride monohydrate.

ABSTRACT: The title compound, C(9)H(11)N(2)O(5) (+)·Cl(-)·H(2)O, was synthesized from (1S,2S)-2-amino-1-(4-nitro-phen-yl)propane-1,3-diol in four steps. As demonstrated by this work, no racemization occurs during this synthetic procedure. The crystal structure displays many inter-molecular hydrogen bonds between the acidic cation, chloride anions and the water mol-ecules, forming a three-dimensional network. An intra-molecular bond between the ammonium group and a hydroxyl O atom is also present.

SUBMITTER: Gaumet V 

PROVIDER: S-EPMC2961501 | biostudies-other | 2008

REPOSITORIES: biostudies-other

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(2R,3S)-2-Ammonio-3-hydr-oxy-3-(4-nitro-phen-yl)propanoic acid chloride monohydrate.

Gaumet Vincent V   Weber Valérie V   Zaitsev Valery P VP   Madesclaire Michel M  

Acta crystallographica. Section E, Structure reports online 20080507 Pt 6

The title compound, C(9)H(11)N(2)O(5) (+)·Cl(-)·H(2)O, was synthesized from (1S,2S)-2-amino-1-(4-nitro-phen-yl)propane-1,3-diol in four steps. As demonstrated by this work, no racemization occurs during this synthetic procedure. The crystal structure displays many inter-molecular hydrogen bonds between the acidic cation, chloride anions and the water mol-ecules, forming a three-dimensional network. An intra-molecular bond between the ammonium group and a hydroxyl O atom is also present. ...[more]

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