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Penta-aqua-(1H-benzimidazole-5,6-di-carboxyl-ato-?N)copper(II) penta-hydrate.

ABSTRACT: The title compound, [Cu(C(9)H(4)N(2)O(4))(H(2)O)(5)]·5H(2)O, contains one crystallographically independent Cu(II) atom and one 1H-benzimidazole-5,6-dicarboxyl-ate (bdc) ligand, along with five coordinated and five uncoordinated water mol-ecules. The Cu(II) atom is six-coordinated by one N atom from the bdc ligand and five O atoms from water mol-ecules, giving an octa-hedral coordination geometry. Hydrogen bonds link the mononuclear complex and uncoordinated water mol-ecules into a three-dimensional network.

SUBMITTER: Gao Q

PROVIDER: S-EPMC2961800 | biostudies-other | 2008

REPOSITORIES: biostudies-other

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Penta-aqua-(1H-benzimidazole-5,6-di-carboxyl-ato-κN)copper(II) penta-hydrate.

Gao Qian Q Gao Wei-Hong WH Zhang Chao-Yan CY Xie Ya-Bo YB

Acta crystallographica. Section E, Structure reports online 20080619 Pt 7

The title compound, [Cu(C(9)H(4)N(2)O(4))(H(2)O)(5)]·5H(2)O, contains one crystallographically independent Cu(II) atom and one 1H-benzimidazole-5,6-dicarboxyl-ate (bdc) ligand, along with five coordinated and five uncoordinated water mol-ecules. The Cu(II) atom is six-coordinated by one N atom from the bdc ligand and five O atoms from water mol-ecules, giving an octa-hedral coordination geometry. Hydrogen bonds link the mononuclear complex and uncoordinated water mol-ecules into a three-dimensio ...[more]

PMID: 21202783

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