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Hexakis(dimethyl sulfoxide-?O)chromium(III) trichloride.

ABSTRACT: In the title compound, [Cr(C(2)H(6)OS)(6)]Cl(3), each Cr(III) ion is located on a three-fold inversion axis and is coordinated by six dimethyl-sulfoxide ligands [Cr-O = 1.970?(2)-1.972?(2)?Å; O-Cr-O = 88.19?(9) and 91.81?(9)°] in a slightly distorted octa-hedral geometry. The Cl(-) anions take part in the formation of weak C-H?Cl hydrogen bonds, which contribute to the crystal packing stabilization.

SUBMITTER: Mikhaylichenko YM

PROVIDER: S-EPMC2961805 | biostudies-other | 2008

REPOSITORIES: biostudies-other

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Hexakis(dimethyl sulfoxide-κO)chromium(III) trichloride.

Mikhaylichenko Yuliya M YM Haukka Matti M Pavlenko Vadim O VO Fritsky Igor O IO Iskenderov Turganbay S TS

Acta crystallographica. Section E, Structure reports online 20080613 Pt 7

In the title compound, [Cr(C(2)H(6)OS)(6)]Cl(3), each Cr(III) ion is located on a three-fold inversion axis and is coordinated by six dimethyl-sulfoxide ligands [Cr-O = 1.970 (2)-1.972 (2) Å; O-Cr-O = 88.19 (9) and 91.81 (9)°] in a slightly distorted octa-hedral geometry. The Cl(-) anions take part in the formation of weak C-H⋯Cl hydrogen bonds, which contribute to the crystal packing stabilization. ...[more]

PMID: 21202768

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