Ontology highlight
ABSTRACT:
SUBMITTER: Li CY
PROVIDER: S-EPMC2961816 | biostudies-other | 2008
REPOSITORIES: biostudies-other
Acta crystallographica. Section E, Structure reports online 20080607 Pt 7
The title compound, [CoBr(2)(C(18)H(12)N(6)S)], is a mononuclear complex in which a twofold rotation axis passes through the Co and S atoms. The Co(II) center is six-coordinated by four N atoms from one bis-[4-(2-pyrid-yl)pyrimidin-2-yl] sulfide (L) ligand and two bromide anions, forming an octa-hedral coordination geometry, where the four donor N atoms are located in the equatorial plane and the Br atoms occupy the axial positions. The sum of the bond angles around the Co atom in the equatorial ...[more]