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1-(4-Chloro-phen-yl)piperazine-1,4-diium tetra-chlorido-zincate(II) monohydrate.

ABSTRACT: In the crystal structure of the title compound, (C(10)H(15)ClN(2))[ZnCl(4)]·H(2)O, the Zn atom is coordinated by four Cl atoms in a tetrahedral geometry. The water mol-ecules and the 1-(4-chloro-phen-yl)piperazine-1,4-diium cations inter-act with the [ZnCl(4)](2-) anions through O-H?Cl, N-H?Cl, N-H?O and C-H?Cl hydrogen bonds (five simple and one bifurcated). Inter-molecular ?-? stacking inter-actions are present between adjacent aromatic rings of 1-(4-chloro-phenyl)-piperazine-1,4-diium cations (the centroid-centroid distance is 3.453?Å).

SUBMITTER: Ben Gharbia I

PROVIDER: S-EPMC2961817 | biostudies-other | 2008

REPOSITORIES: biostudies-other

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1-(4-Chloro-phen-yl)piperazine-1,4-diium tetra-chlorido-zincate(II) monohydrate.

Ben Gharbia Imen I Kefi Riadh R El Glaoui Meher M Jeanneau Erwann E Ben Nasr Cherif C

Acta crystallographica. Section E, Structure reports online 20080607 Pt 7

In the crystal structure of the title compound, (C(10)H(15)ClN(2))[ZnCl(4)]·H(2)O, the Zn atom is coordinated by four Cl atoms in a tetrahedral geometry. The water mol-ecules and the 1-(4-chloro-phen-yl)piperazine-1,4-diium cations inter-act with the [ZnCl(4)](2-) anions through O-H⋯Cl, N-H⋯Cl, N-H⋯O and C-H⋯Cl hydrogen bonds (five simple and one bifurcated). Inter-molecular π-π stacking inter-actions are present between adjacent aromatic rings of 1-(4-chloro-phenyl)-piperazine-1,4-diium cations ...[more]

PMID: 21202751

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