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Tetra-kis(1-ethyl-3-methyl-imidazolium) ?-hexa-cosa-oxidoocta-molybdate.

ABSTRACT: The title compound, (C(6)H(11)N(2))(4)[Mo(8)O(26)] or (emim)(4)[?-Mo(8)O(26)] (emim is 1-ethyl-3-methyl-imidazolium), was obtained from the ionic liquid [emim]BF(4). The asymmetric unit contains two [emim](+) cations and one-half of the [?-Mo(8)O(26)](4-) tetra-anion, which occupies a special position on an inversion centre. The ?-[Mo(8)O(26)](4-) tetra-anion features eight distorted MoO(6) coordination octa-hedra linked together through bridging O atoms.

SUBMITTER: Lin S

PROVIDER: S-EPMC2961847 | biostudies-other | 2008

REPOSITORIES: biostudies-other

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Tetra-kis(1-ethyl-3-methyl-imidazolium) β-hexa-cosa-oxidoocta-molybdate.

Lin Shiwei S Chen Weilin W Zhang Zhiming Z Liu Wenli W Wang Enbo E

Acta crystallographica. Section E, Structure reports online 20080621 Pt 7

The title compound, (C(6)H(11)N(2))(4)[Mo(8)O(26)] or (emim)(4)[β-Mo(8)O(26)] (emim is 1-ethyl-3-methyl-imidazolium), was obtained from the ionic liquid [emim]BF(4). The asymmetric unit contains two [emim](+) cations and one-half of the [β-Mo(8)O(26)](4-) tetra-anion, which occupies a special position on an inversion centre. The β-[Mo(8)O(26)](4-) tetra-anion features eight distorted MoO(6) coordination octa-hedra linked together through bridging O atoms. ...[more]

PMID: 21202803

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