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Tetra-chlorido(4,4'-dimethyl-2,2'-bipyridine-?N,N')platinum(IV).

ABSTRACT: The asymmetric unit of the title compound, [PtCl(4)(C(12)H(12)N(2))], contains one half-mol-ecule; a twofold rotation axis passes through the Pt atom and the mid-point of the C-C bond linking the two rings. The Pt(IV) atom is six-coordinated in an octa-hedral configuration by two N atoms of the 4,4'-dimethyl-2,2'-bipyridine ligand and four terminal Cl atoms. In the crystal structure, there are weak ?-? inter-actions between pyridine rings, with a centroid-centroid distance of 4.365?(3)?Å.

SUBMITTER: Hojjat Kashani L

PROVIDER: S-EPMC2961848 | biostudies-other | 2008

REPOSITORIES: biostudies-other

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Tetra-chlorido(4,4'-dimethyl-2,2'-bipyridine-κN,N')platinum(IV).

Hojjat Kashani Leila L Amani Vahid V Yousefi Mohammad M Khavasi Hamid Reza HR

Acta crystallographica. Section E, Structure reports online 20080613 Pt 7

The asymmetric unit of the title compound, [PtCl(4)(C(12)H(12)N(2))], contains one half-mol-ecule; a twofold rotation axis passes through the Pt atom and the mid-point of the C-C bond linking the two rings. The Pt(IV) atom is six-coordinated in an octa-hedral configuration by two N atoms of the 4,4'-dimethyl-2,2'-bipyridine ligand and four terminal Cl atoms. In the crystal structure, there are weak π-π inter-actions between pyridine rings, with a centroid-centroid distance of 4.365 (3) Å. ...[more]

PMID: 21202769

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