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Bis(N,N-diethyl-dithio-carbamato)(1,10-phenanthroline)cobalt(III) tetra-fluorido-borate.

ABSTRACT: The cationic complex in the structure of the title compound, [Co(Et(2)NCS(2))(2)(C(12)H(8)N(2))]BF(4), has a Co(III) atom with a distorted octa-hedral coordination formed by four S atoms of two diethyl-dithio-carbamate and two N atoms of 1,10-phenanthroline ligands. The crystal structure features head-to-tail stacking of the phenanthroline ligands. The tetra-fluorido-borate anions are positioned in the channels between the cation stacks running along the a axis, and form weak C-H?F interactions.

SUBMITTER: Boyd PD 

PROVIDER: S-EPMC2961857 | biostudies-other | 2008

REPOSITORIES: biostudies-other

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Bis(N,N-diethyl-dithio-carbamato)(1,10-phenanthroline)cobalt(III) tetra-fluorido-borate.

Boyd Peter D W PD   Rickard Clifton E F CE  

Acta crystallographica. Section E, Structure reports online 20080613 Pt 7

The cationic complex in the structure of the title compound, [Co(Et(2)NCS(2))(2)(C(12)H(8)N(2))]BF(4), has a Co(III) atom with a distorted octa-hedral coordination formed by four S atoms of two diethyl-dithio-carbamate and two N atoms of 1,10-phenanthroline ligands. The crystal structure features head-to-tail stacking of the phenanthroline ligands. The tetra-fluorido-borate anions are positioned in the channels between the cation stacks running along the a axis, and form weak C-H⋯F interactions. ...[more]