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Tetracarbon-ylbis(?-cyclo-penta-dien-yl)bis(diphenyl-phosphine)dimolybdenum(Mo-Mo) hexane solvate.

ABSTRACT: The title compound, [Mo(2)(C(5)H(5))(2)(C(12)H(11)P)(2)(CO)(4)]·C(6)H(14), is a centrosymmetric Mo complex in which two Mo atoms are connected by an Mo-Mo bond [3.2072?(12)?Å]. Each Mo atom is coordinated by an ?(5)-cyclo-penta-dienyl ligand, two carbonyl ligands and a diphenyl-phosphine ligand in a piano-stool fashion.

SUBMITTER: Shultz GV 

PROVIDER: S-EPMC2961865 | biostudies-other | 2008

REPOSITORIES: biostudies-other

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Tetracarbon-ylbis(η-cyclo-penta-dien-yl)bis(diphenyl-phosphine)dimolybdenum(Mo-Mo) hexane solvate.

Shultz Ginger V GV   Bossé Stephanie A SA   Zakharov Lev N LN   Tyler David R DR  

Acta crystallographica. Section E, Structure reports online 20080619 Pt 7

The title compound, [Mo(2)(C(5)H(5))(2)(C(12)H(11)P)(2)(CO)(4)]·C(6)H(14), is a centrosymmetric Mo complex in which two Mo atoms are connected by an Mo-Mo bond [3.2072 (12) Å]. Each Mo atom is coordinated by an η(5)-cyclo-penta-dienyl ligand, two carbonyl ligands and a diphenyl-phosphine ligand in a piano-stool fashion. ...[more]