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2-Bromo-4-chloro-6-(4-fluoro-phenyl-imino-meth-yl)phenol.

ABSTRACT: The two mol-ecules of the title compound, C(13)H(8)BrClFNO, in the asymmetric unit are inter-connected by ?-? inter-actions between the salicylaldehyde and aniline units, the shortest inter-planar distance being 3.317?(3)?Å. These pairs and their translation equivalents are further linked by C-H?F hydrogen bonds, forming a one-dimensional infinite chain. In addition, there is an intra-molecular O-H?N hydrogen bond connecting the OH group and the imine N atom.

SUBMITTER: Puthilibai G 

PROVIDER: S-EPMC2961884 | biostudies-other | 2008

REPOSITORIES: biostudies-other

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2-Bromo-4-chloro-6-(4-fluoro-phenyl-imino-meth-yl)phenol.

Puthilibai G G   Vasudhevan S S   Rajagopal G G  

Acta crystallographica. Section E, Structure reports online 20080625 Pt 7

The two mol-ecules of the title compound, C(13)H(8)BrClFNO, in the asymmetric unit are inter-connected by π-π inter-actions between the salicylaldehyde and aniline units, the shortest inter-planar distance being 3.317 (3) Å. These pairs and their translation equivalents are further linked by C-H⋯F hydrogen bonds, forming a one-dimensional infinite chain. In addition, there is an intra-molecular O-H⋯N hydrogen bond connecting the OH group and the imine N atom. ...[more]

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