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Tris(2,2'-bipyridine-?N,N')cadmium(II) bis-(perchlorate) hemihydrate.

ABSTRACT: The asymmetric unit of the title compound, [Cd(C(10)H(8)N(2))(3)](ClO(4))(2)·0.5H(2)O, consists of one complex [Cd(bpy)(3)](2+) cation (bpy = 2,2'-bipyridine), two perchlorate anions and one water molecule with half-occupancy. The central cadmium(II) ion is bound to six N atoms from three bpy ligands in a distorted octa-hedral coordination, with Cd-N bond distances ranging from 2.304?(3) to 2.395?(2)?Å.

SUBMITTER: Zhang W 

PROVIDER: S-EPMC2967850 | biostudies-other | 2008

REPOSITORIES: biostudies-other

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Tris(2,2'-bipyridine-κN,N')cadmium(II) bis-(perchlorate) hemihydrate.

Zhang Weiguang W   Jiang Zhengjing Z   Lu Lude L  

Acta crystallographica. Section E, Structure reports online 20081203 Pt 1

The asymmetric unit of the title compound, [Cd(C(10)H(8)N(2))(3)](ClO(4))(2)·0.5H(2)O, consists of one complex [Cd(bpy)(3)](2+) cation (bpy = 2,2'-bipyridine), two perchlorate anions and one water molecule with half-occupancy. The central cadmium(II) ion is bound to six N atoms from three bpy ligands in a distorted octa-hedral coordination, with Cd-N bond distances ranging from 2.304 (3) to 2.395 (2) Å. ...[more]

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