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Dichlorido(di-2-pyridylamine)mercury(II).

ABSTRACT: In the mol-ecule of the title compound, [HgCl(2)(C(10)H(9)N(3))], the Hg(II) atom is four-coordinated in a distorted tetra-hedral configuration by two N atoms from the chelating di-2-pyridylamine ligand and by two Cl atoms. In the crystal structure, inter-molecular N-H?Cl hydrogen bonds link the mol-ecules into centrosymmetric dimers. There is a ?-? contact between the pyridine rings [centroid-centroid distance = 3.896?(5)?Å].

SUBMITTER: Yousefi M

PROVIDER: S-EPMC2967852 | biostudies-other | 2008

REPOSITORIES: biostudies-other

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Dichlorido(di-2-pyridylamine)mercury(II).

Yousefi Mohammad M Allahgholi Ghasri Mohammad Reza MR Heidari Amene A Amani Vahid V

Acta crystallographica. Section E, Structure reports online 20081206 Pt 1

In the mol-ecule of the title compound, [HgCl(2)(C(10)H(9)N(3))], the Hg(II) atom is four-coordinated in a distorted tetra-hedral configuration by two N atoms from the chelating di-2-pyridylamine ligand and by two Cl atoms. In the crystal structure, inter-molecular N-H⋯Cl hydrogen bonds link the mol-ecules into centrosymmetric dimers. There is a π-π contact between the pyridine rings [centroid-centroid distance = 3.896 (5) Å]. ...[more]

PMID: 21581552

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