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(2,2'-Bipyridine)(2-formyl-6-methoxy-phenolato)nickel(II) perchlorate.

ABSTRACT: In the title compound, [Ni(C(8)H(7)O(3))(C(10)H(8)N(2))]ClO(4), the Ni(II) atom is in a slightly distorted square-planar coordination by two N atoms from the 2,2'-bipyridine (bipy) ligand and two O atoms from the deprotonated 2-formyl-6-methoxy-phenolate (mbd) ligand. The bipy ligand is nearly coplanar with the Ni(II) square plane, the Ni atom being only 0.042?(2)?Å from the mean plane, whereas the benzaldehyde plane is folded with respect to the square plane, making a dihedral angle of 19.17?(8)°. One of the O atoms of the perchlorate anion is involved in a weak inter-action with the Ni atom, with an Ni-O distance of 2.5732?(18)?Å. The packing is stabilized by weak C-H?O inter-actions.

SUBMITTER: Wang CJ

PROVIDER: S-EPMC2967862 | biostudies-other | 2008

REPOSITORIES: biostudies-other

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(2,2'-Bipyridine)(2-formyl-6-methoxy-phenolato)nickel(II) perchlorate.

Wang Cui-Juan CJ Ren Ping-Di PD Wu Wei-Ping WP Zhang Zhi-Bin ZB

Acta crystallographica. Section E, Structure reports online 20081206 Pt 1

In the title compound, [Ni(C(8)H(7)O(3))(C(10)H(8)N(2))]ClO(4), the Ni(II) atom is in a slightly distorted square-planar coordination by two N atoms from the 2,2'-bipyridine (bipy) ligand and two O atoms from the deprotonated 2-formyl-6-methoxy-phenolate (mbd) ligand. The bipy ligand is nearly coplanar with the Ni(II) square plane, the Ni atom being only 0.042 (2) Å from the mean plane, whereas the benzaldehyde plane is folded with respect to the square plane, making a dihedral angle of 19.17 (8 ...[more]

PMID: 21581476

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