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Trans-Dimethano-lbis(1,1,1-trifluoro-5,5-dimethyl-hexane-2,4-dionato)zinc(II).


ABSTRACT: The title compound, [Zn(C(8)H(10)F(3)O(2))(2)(CH(4)O)(2)], is a dimethanol coordinated zinc complex with the acetyl acetonate derivative 1,1,1-trifluoro-5,5-dimethyl-hexane-2,4-dionate. The bis--?-diketonate complex, which is isostructural with its Co analogue, is located on a crystallographic inversion center. The complex is octa-hedral with basically no distortion, and the methanol mol-ecules are in trans positions with respect to one another. The planes of the ?-diketonate and the ZnO(4) unit are tilted by 18.64?(10)° against each other. O-H?O hydrogen bonds between the methanol hydroxyl groups and neighboring diketonate O atoms create chains running along [100].

SUBMITTER: Hunter GO 

PROVIDER: S-EPMC2967872 | biostudies-other | 2008

REPOSITORIES: biostudies-other

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trans-Dimethano-lbis(1,1,1-trifluoro-5,5-dimethyl-hexane-2,4-dionato)zinc(II).

Hunter Gerald O GO   Zeller Matthias M   Leskiw Brian D BD  

Acta crystallographica. Section E, Structure reports online 20081210 Pt 1


The title compound, [Zn(C(8)H(10)F(3)O(2))(2)(CH(4)O)(2)], is a dimethanol coordinated zinc complex with the acetyl acetonate derivative 1,1,1-trifluoro-5,5-dimethyl-hexane-2,4-dionate. The bis--β-diketonate complex, which is isostructural with its Co analogue, is located on a crystallographic inversion center. The complex is octa-hedral with basically no distortion, and the methanol mol-ecules are in trans positions with respect to one another. The planes of the β-diketonate and the ZnO(4) unit  ...[more]

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