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Triaqua-(2,2'-bipyridine)(5-nitro-isophthal-ato-?O)nickel(II) monohydrate.

ABSTRACT: In the title compound, [Ni(C(8)H(3)NO(6))(C(10)H(8)N(2))(H(2)O)(3)]·H(2)O, the Ni(II) cation is six-coordinated by a chelating 2,2'-bipyridine ligand, one carboxyl-ate O atom from a 5-nitro-isophthalate dianion and three water mol-ecules, with a slightly distorted cis-NiN(2)O(4) octa-hedral geometry. The neutral complex is isolated, in contrast to coordination polymers formed by Mn(II), Co(II) and Cu(II) with the same ligand set, but forms an extensive network of O-H?O hydrogen bonds between the coordinated and uncoordinated water mol-ecules and carboxyl-ate groups of the 5-nitro-isophthalate ions.

SUBMITTER: Liu Y 

PROVIDER: S-EPMC2967874 | biostudies-other | 2008

REPOSITORIES: biostudies-other

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Triaqua-(2,2'-bipyridine)(5-nitro-isophthal-ato-κO)nickel(II) monohydrate.

Liu Ying Y   He Qingpeng Q   Zhang Xianxi X   Xue Zechun Z   Lv Chunyan C  

Acta crystallographica. Section E, Structure reports online 20081210 Pt 1

In the title compound, [Ni(C(8)H(3)NO(6))(C(10)H(8)N(2))(H(2)O)(3)]·H(2)O, the Ni(II) cation is six-coordinated by a chelating 2,2'-bipyridine ligand, one carboxyl-ate O atom from a 5-nitro-isophthalate dianion and three water mol-ecules, with a slightly distorted cis-NiN(2)O(4) octa-hedral geometry. The neutral complex is isolated, in contrast to coordination polymers formed by Mn(II), Co(II) and Cu(II) with the same ligand set, but forms an extensive network of O-H⋯O hydrogen bonds between the  ...[more]

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