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Catena-Poly[[trimethyl-tin(IV)]-?-2,4,6-trichloro-benzoato].

ABSTRACT: In the title compound, [Sn(CH(3))(3)(C(7)H(2)Cl(3)O(2))](n), the tin(IV) atom exhibits a slightly distorted trigonal-bipyramidal geometry with two O atoms of symmetry-related carboxyl-ate groups in the axial positions and three methyl groups in the equatorial positions. In the crystal structure, the metal atoms are linked by carboxyl-ate bridges into polymeric chains extending along the b axis.

SUBMITTER: Wen L

PROVIDER: S-EPMC2967877 | biostudies-other | 2008 Dec

REPOSITORIES: biostudies-other

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catena-Poly[[trimethyl-tin(IV)]-μ-2,4,6-trichloro-benzoato].

Wen Liyuan L Yin Handong H Li Wenkuan W Wang Daqi D

Acta crystallographica. Section E, Structure reports online 20081210 Pt 1

In the title compound, [Sn(CH(3))(3)(C(7)H(2)Cl(3)O(2))](n), the tin(IV) atom exhibits a slightly distorted trigonal-bipyramidal geometry with two O atoms of symmetry-related carboxyl-ate groups in the axial positions and three methyl groups in the equatorial positions. In the crystal structure, the metal atoms are linked by carboxyl-ate bridges into polymeric chains extending along the b axis. ...[more]

PMID: 21581503

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