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Catena-Poly[[trimethyl-tin(IV)]-?-2-(3-thien-yl)acetato].

ABSTRACT: The title compound, [Sn(CH(3))(3)(C(6)H(5)O(2)S)](n), forms an infinite chain structure parallel to [100]. There are two mol-ecules of the complex in the asymmetric unit. The geometry of the Sn atoms in both mol-ecules is distorted trigonal-bipyramidal. The S and C atoms of the thio-phene rings in both mol-ecules are disordered over two sites with site-occupancy factors 0.799?(9)/0.201?(9) and 0.618?(7)/0.382?(7), respectively.

SUBMITTER: Yang M

PROVIDER: S-EPMC2967881 | biostudies-other | 2008

REPOSITORIES: biostudies-other

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catena-Poly[[trimethyl-tin(IV)]-μ-2-(3-thien-yl)acetato].

Yang Minglei M Yin Handong H Wen Liyuan L Li Wenkuan W Wang Daqi D

Acta crystallographica. Section E, Structure reports online 20081210 Pt 1

The title compound, [Sn(CH(3))(3)(C(6)H(5)O(2)S)](n), forms an infinite chain structure parallel to [100]. There are two mol-ecules of the complex in the asymmetric unit. The geometry of the Sn atoms in both mol-ecules is distorted trigonal-bipyramidal. The S and C atoms of the thio-phene rings in both mol-ecules are disordered over two sites with site-occupancy factors 0.799 (9)/0.201 (9) and 0.618 (7)/0.382 (7), respectively. ...[more]

PMID: 21581507

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