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[4-Chloro-N'-(3-meth-oxy-2-oxidobenzyl-idene)benzohydrazidato]dimethyl-tin(IV).

ABSTRACT: In the title mol-ecule, [Sn(CH(3))(2)(C(15)H(11)ClN(2)O(3))], the two benzene rings form a dihedral angle of 6.37?(2)°. The Sn atom is coordinated by one N [Sn-N = 2.187?(3)?Å], two O [Sn-O = 2.123?(3) and 2.174?(3)?Å] and two C [Sn-C = 2.096?(4) and 2.101?(4)?Å] atoms in a distorted trigonal-bipyramidal geometry. The crystal packing exhibits weak inter-molecular C-H?O hydrogen bonds, which link the mol-ecules into centrosymmetric dimers with an Sn?Sn separation of 4.330?(6)?Å, and ?-? inter-actions [centroid-centroid distance of 3.690?(5)?Å between the benzene rings of neighbouring mol-ecules].

SUBMITTER: Cui J 

PROVIDER: S-EPMC2967882 | biostudies-other | 2008

REPOSITORIES: biostudies-other

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[4-Chloro-N'-(3-meth-oxy-2-oxidobenzyl-idene)benzohydrazidato]dimethyl-tin(IV).

Cui Jichun J   Qiao Yanling Y   Yin Handong H  

Acta crystallographica. Section E, Structure reports online 20081210 Pt 1

In the title mol-ecule, [Sn(CH(3))(2)(C(15)H(11)ClN(2)O(3))], the two benzene rings form a dihedral angle of 6.37 (2)°. The Sn atom is coordinated by one N [Sn-N = 2.187 (3) Å], two O [Sn-O = 2.123 (3) and 2.174 (3) Å] and two C [Sn-C = 2.096 (4) and 2.101 (4) Å] atoms in a distorted trigonal-bipyramidal geometry. The crystal packing exhibits weak inter-molecular C-H⋯O hydrogen bonds, which link the mol-ecules into centrosymmetric dimers with an Sn⋯Sn separation of 4.330 (6) Å, and π-π inter-act  ...[more]

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