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Aqua-(imino-diacetato-?O,N,O')(1,10-phenanthroline-?N,N')cobalt(II) monohydrate.

ABSTRACT: The imino-diacetate dianion in the title compound, [Co(C(4)H(5)NO(4))(C(12)H(8)N(2))(H(2)O)]·H(2)O, chelates to the cobalt(II) atom, its N and two O atoms occupying the fac sites of the distorted octa-hedron around the metal atom. The metal atom is also chelated by the N-heterocycle. The dianion, and coordinated and uncoordinated water mol-ecules inter-act through hydrogen bonds, generating a layer motif. The crystal studied was a racemic twin with a 0.62?(2):0.38?(2) domain ratio.

SUBMITTER: Ng HL

PROVIDER: S-EPMC2967887 | biostudies-other | 2008

REPOSITORIES: biostudies-other

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Aqua-(imino-diacetato-κO,N,O')(1,10-phenanthroline-κN,N')cobalt(II) monohydrate.

Ng Hwa Loong HL Ng Chew Hee CH Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20081210 Pt 1

The imino-diacetate dianion in the title compound, [Co(C(4)H(5)NO(4))(C(12)H(8)N(2))(H(2)O)]·H(2)O, chelates to the cobalt(II) atom, its N and two O atoms occupying the fac sites of the distorted octa-hedron around the metal atom. The metal atom is also chelated by the N-heterocycle. The dianion, and coordinated and uncoordinated water mol-ecules inter-act through hydrogen bonds, generating a layer motif. The crystal studied was a racemic twin with a 0.62 (2):0.38 (2) domain ratio. ...[more]

PMID: 21581514

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