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Chlorido{N,N'-o-phenyl-ene-[6,6'-ethyl-enebis(pyridine-2-carboxamide)]}iron(III).

ABSTRACT: In the title compound, [Fe(C(20)H(14)N(4)O(2))Cl], the Fe(III) ion is in a distorted square-pyramidal environment, with two pyridine and two deprotonated amide N atoms in the basal plane and the Cl ion in the apical position. The Fe(III) ion is displaced from the basal plane of the square- pyramid towards the apical Cl atom by 0.2942?(4)?Å. The mol-ecules are linked into a three-dimensional network by C-H?Cl and C-H?O hydrogen bonds.

SUBMITTER: Yang L 

PROVIDER: S-EPMC2967889 | biostudies-other | 2008 Dec

REPOSITORIES: biostudies-other

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Chlorido{N,N'-o-phenyl-ene-[6,6'-ethyl-enebis(pyridine-2-carboxamide)]}iron(III).

Yang Li L   Tang Bin B  

Acta crystallographica. Section E, Structure reports online 20081210 Pt 1

In the title compound, [Fe(C(20)H(14)N(4)O(2))Cl], the Fe(III) ion is in a distorted square-pyramidal environment, with two pyridine and two deprotonated amide N atoms in the basal plane and the Cl ion in the apical position. The Fe(III) ion is displaced from the basal plane of the square- pyramid towards the apical Cl atom by 0.2942 (4) Å. The mol-ecules are linked into a three-dimensional network by C-H⋯Cl and C-H⋯O hydrogen bonds. ...[more]

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