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[Benzyl(2-pyridylmeth-yl)amine]dichloridomercury(II).

ABSTRACT: The Hg atom in the title compound, [HgCl(2)(C(13)H(14)N(2))], adopts a distorted tetra-hedral geometry, being ligated by two N atoms of the benzyl(2-pyridylmeth-yl)amine (bpma) ligand and two Cl atoms. The dihedral angle between the least-squares planes through the chelate ring and Cl-Hg-Cl atoms is 85.4?(1)°. The phenyl ring on the bpma ligand is twisted out of the pyridine plane, forming a dihedral angle of 76.0?(3)°. Disorder in this ring is also noted with two coplanar conformations having equal site occupancies.

SUBMITTER: Seo HJ

PROVIDER: S-EPMC2967898 | biostudies-other | 2008

REPOSITORIES: biostudies-other

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[Benzyl(2-pyridylmeth-yl)amine]dichloridomercury(II).

Seo Hoe-Joo HJ Kim Young-Inn YI Lee You-Soon YS Kang Sung Kwon SK

Acta crystallographica. Section E, Structure reports online 20081213 Pt 1

The Hg atom in the title compound, [HgCl(2)(C(13)H(14)N(2))], adopts a distorted tetra-hedral geometry, being ligated by two N atoms of the benzyl(2-pyridylmeth-yl)amine (bpma) ligand and two Cl atoms. The dihedral angle between the least-squares planes through the chelate ring and Cl-Hg-Cl atoms is 85.4 (1)°. The phenyl ring on the bpma ligand is twisted out of the pyridine plane, forming a dihedral angle of 76.0 (3)°. Disorder in this ring is also noted with two coplanar conformations having e ...[more]

PMID: 21581525

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[Bis(2-pyridylmeth-yl)amine]dichloridomercury(II).

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N-[2-(Phenyl-sulfon-yl)eth-yl]benzyl-amine.

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