Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

[Benzyl(2-pyridylmeth-yl)amine]dichloridomercury(II).

ABSTRACT: The Hg atom in the title compound, [HgCl(2)(C(13)H(14)N(2))], adopts a distorted tetra-hedral geometry, being ligated by two N atoms of the benzyl(2-pyridylmeth-yl)amine (bpma) ligand and two Cl atoms. The dihedral angle between the least-squares planes through the chelate ring and Cl-Hg-Cl atoms is 85.4?(1)°. The phenyl ring on the bpma ligand is twisted out of the pyridine plane, forming a dihedral angle of 76.0?(3)°. Disorder in this ring is also noted with two coplanar conformations having equal site occupancies.

SUBMITTER: Seo HJ

PROVIDER: S-EPMC2967898 | biostudies-other | 2008

REPOSITORIES: biostudies-other

ACCESS DATA

Json Xml

Publications

[Benzyl(2-pyridylmeth-yl)amine]dichloridomercury(II).

Seo Hoe-Joo HJ Kim Young-Inn YI Lee You-Soon YS Kang Sung Kwon SK

Acta crystallographica. Section E, Structure reports online 20081213 Pt 1

The Hg atom in the title compound, [HgCl(2)(C(13)H(14)N(2))], adopts a distorted tetra-hedral geometry, being ligated by two N atoms of the benzyl(2-pyridylmeth-yl)amine (bpma) ligand and two Cl atoms. The dihedral angle between the least-squares planes through the chelate ring and Cl-Hg-Cl atoms is 85.4 (1)°. The phenyl ring on the bpma ligand is twisted out of the pyridine plane, forming a dihedral angle of 76.0 (3)°. Disorder in this ring is also noted with two coplanar conformations having e ...[more]

PMID: 21581525

Similar Datasets

[(6-Methyl-2-pyridylmeth-yl)(2-pyridylmeth-yl)amine][(2-pyridylmeth-yl)amine]copper(II) bis-(perchlorate).

Project description:The title compound, [Cu(C(6)H(8)N(2))(C(13)H(15)N(3))](ClO(4))(2), is a mixed ligand complex with the Cu(II) atom coordinated by (6-methyl-2-pyridylmeth-yl)(2-pyridylmeth-yl)amine, acting as a tridentate ligand, and 2-(2-amino-meth-yl)pyridine, as a bidentate ligand, leading to an N(5) square-pyramidal geometry. The amine H atoms are involved in hydrogen bonding to the perchlorate O atoms and there are extensive but weak inter-molecular C-H⋯O inter-actions in the crystal structure. The perchlorate ions are each disordered over two positions, with site occupancies of 0.601 (8):0.399 (8) and 0.659 (11):0.341 (11).

| S-EPMC2914953 | biostudies-literature

[Bis(2-pyridylmeth-yl)amine]dichloridomercury(II).

Project description:The Hg atom in the title complex, [HgCl(2)(C(12)H(13)N(3))], adopts a square-pyramidal geometry, being ligated by three N atoms of the tridentate bis-(2-pyridylmeth-yl)amine ligand and two Cl atoms, with one of the latter occupying the apical position. Disorder is noted in the amine portion of the ligand and this was modelled over two sites, with the major component having a site-occupancy factor of 0.794 (14).

| S-EPMC2960290 | biostudies-literature

(Dicyanamido)[tris-(2-pyridylmeth-yl)amine]zinc(II) perchlorate.

Project description:In the title complex, [Zn(C(2)N(3))(C(18)H(18)N(4))]ClO(4), the Zn(II) ion has a slightly distorted trigonal-bipyramidal ZnN(5) coordination geometry. The crystal structure is stabilized by weak inter-molecular C-H?O and C-H?N hydrogen bonds. In addition, there are relatively close contacts between the O atoms of the perchlorate anion and symmetry-related pyridine rings [O?Cg = 3.179?(3) and 3.236?(3)?Å, where Cg is the centroid of a pyridine ring], and between the terminal N atom of the dicyanamide ligand and pyridine rings [N?Cg = 3.381?(4)-3.761?(3)?Å]. The central N atom of the dicyanamide ligand is disordered over two sites in an approximately 0.6:0.4 ratio.

| S-EPMC2960752 | biostudies-literature

(Acetonitrile)[bis-(2-pyridylmeth-yl)amine]bis-(perchlorato)copper(II).

Project description:In the title compound, [Cu(ClO(4))(2)(C(12)H(13)N(3))(C(2)H(3)N)], the Cu(II) atom is six-coordinate in a Jahn-Teller distorted octahedral geometry, with coordination by the tridentate chelating ligand, an acetonitrile mol-ecule, and two axial perchlorate anions. The tridentate ligand bis-(2-pyridylmeth-yl)amine chelates meridionally and equatorially while an acetonitrile mol-ecule is coordinated at the fourth equatorial site. The two perchlorate anions are disordered with site occupancy factors of 0.72/0.28. The amine H is involved in intra-molecular hydrogen bonding to the perchlorate O atoms and there are extensive but weak inter-molecular C-H⋯O inter-actions.

| S-EPMC2915155 | biostudies-literature

N,N-Bis(2-pyridylmeth-yl)-tert-butyl-amine.

Project description:In the title compound, C(16)H(21)N(3), the dihedral angle between the two pyridine rings is 88.11?(9)°. In the crystal, mol-ecules are linked through inter-molecular C-H?? inter-actions, forming a layer expanding parallel to the (10) plane.

| S-EPMC2968317 | biostudies-literature

Bis(thio-cyanato-?N)[tris-(2-pyridylmeth-yl)amine-?N,N',N'',N''']nickel(II) methanol hemisolvate.

Project description:The title complex, [Ni(NCS)(2)(C(18)H(18)N(4))]·0.5CH(3)OH, consists of two crystallographically distinct complexes and a methanol solvent mol-ecule. The Ni(II) complexes are pseudo-octa-hedral six-coordinate, with the tris-(2-pyridylmeth-yl)amine (TPA) ligand providing four N atoms and two N-bound thio-cyanates providing the final two N atoms. The distances and angles are typical for Ni(II)-TPA complexes. The compound has unit-cell parameters that are surprisingly similar to the previously reported hydrate.

| S-EPMC2969451 | biostudies-literature

(SP-4-2)-Chlorido{N-[2-(diphenyl-phosphan-yl)benzyl-idene]benzyl-amine-κP,N}(meth-yl)palladium(II).

Project description:In the title Pd(II) complex, [Pd(CH(3))Cl(C(26)H(22)NP)], the Pd(II) atom is coordinated in a slightly distorted square-planar geometry by the imino N and phosphane P atoms of the ligand, by one chloride ion and by a methyl ligand. The methyl group is trans to the N atom of the ligand.

| S-EPMC3246930 | biostudies-literature

N-[2-(Phenyl-sulfon-yl)eth-yl]benzyl-amine.

Project description:The title compound, C(15)H(17)NO(2)S, exhibits intra-molecular hydrogen bonding between the amine H atom and a sulfonyl O atom. The conformation of the mol-ecule is described by the four PhCH(2)-NH-CH(2)-CH(2)-SO(2)Ph torsion angles of 79.6?(2), -166.21?(14), -70.29?(17) and -58.93?(13)°.

| S-EPMC3470312 | biostudies-literature

μ-Oxido-bis-{chlorido[tris-(2-pyridylmeth-yl)amine]chromium(III)} bis(hexafluoridophosphate).

Project description:The title compound, [Cr(2)Cl(2)O(C(18)H(18)N(4))(2)](PF(6))(2), is isostructural with the V(III) analogue. Each Cr(III) atom is chelated by the tetra-dentate tris-(2-pyridylmeth-yl)amine ligand via four N atoms, and further coordinated by one Cl atom and one bridging O atom, giving a slightly distorted octa-hedral coordination geometry. The dinuclear complex is centrosymmetric, with the bridging O atom lying on a centre of inversion.

| S-EPMC2914886 | biostudies-literature

[N,N-Bis(diphenyl-phosphan-yl)benzyl-amine-κP,P']dichloridonickel(II) dichloro-methane monosolvate.

Project description:In the title solvated complex, [NiCl(2)(C(31)H(27)NP(2))]·CH(2)Cl(2), the Ni(2+) ion is coordinated by two chloride ions and two P atoms of the chelating N,N-bis-(diphenyl-phosphan-yl)benzyl ligand to generate a strongly distorted cis-NiCl(2)P(2) square-planar geometry for the metal ion. In the crystal, the components are linked by C-H⋯Cl inter-actions.

| S-EPMC3246988 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data