Browse
Submit Data
Databases
API
Help

Dataset Information

10 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Chlorido{[2-(dicyclo-hexyl-phosphano-yl)eth-yl]bis-[2-(dicyclo-hexyl-phosphan-yl)eth-yl]phosphane}platinum(II) chloride dichloro-methane hemisolvate tetra-hydrate.

ABSTRACT: The title compound, [PtCl(C(42)H(78)OP(4))]Cl·0.5CH(2)Cl(2)·4H(2)O, crystallizes as a contact ion-pair with two close inter-molecular C-H?Cl(-) contacts between CH acidic ?H atoms of the phosphane ligand and the chloride anion. A chloride ligand together with three coordinating P ligand atoms create a slightly distorted square-planar coordination environment around the Pt(II) center. An inter-molecular water O-H?Cl(-) and water O-H?OP hydrogen-bond network completes the coordination around the anion. In addition, a disordered CH(2)Cl(2) solvent mol-ecule cocrystallized within a hydro-phobic cavity spanned by the dicyclo-hexyl-phosphane ligands.

SUBMITTER: Rieckborn TP

PROVIDER: S-EPMC2967900 | biostudies-other | 2008

REPOSITORIES: biostudies-other

ACCESS DATA

Json Xml

Publications

Chlorido{[2-(dicyclo-hexyl-phosphano-yl)eth-yl]bis-[2-(dicyclo-hexyl-phosphan-yl)eth-yl]phosphane}platinum(II) chloride dichloro-methane hemisolvate tetra-hydrate.

Rieckborn Timo Paul TP Karakoc Emine E He Jin J Prosenc Marc Heinrich MH

Acta crystallographica. Section E, Structure reports online 20081213 Pt 1

The title compound, [PtCl(C(42)H(78)OP(4))]Cl·0.5CH(2)Cl(2)·4H(2)O, crystallizes as a contact ion-pair with two close inter-molecular C-H⋯Cl(-) contacts between CH acidic αH atoms of the phosphane ligand and the chloride anion. A chloride ligand together with three coordinating P ligand atoms create a slightly distorted square-planar coordination environment around the Pt(II) center. An inter-molecular water O-H⋯Cl(-) and water O-H⋯OP hydrogen-bond network completes the coordination around the a ...[more]

PMID: 21581527

Similar Datasets

Bis[dicyclo-hexyl-(phenyl)-phosphane-κP]silver(I) perchlorate dichloro-methane monosolvate.

Project description:In the title compound, [Ag{P(C(6)H(11))(2)(C(6)H(5))}(2)]ClO(4)·CH(2)Cl(2), the Ag(I) atom in the mononuclear complex cation is coordinated by two P atoms of the phosphane ligands [Ag-P = 2.3993 (4) and 2.4011 (4) Å; P-Ag-P = 177.473 (18)°] and the perchlorate anion acts as the counter-anion. There is an Ag⋯O(perchlorate) inter-action of 2.873 (2) Å, which contributes to the slightly non-linear bond angle about the Ag(I) atom. Weak inter-molecular C-H⋯O hydrogen-bonding inter-actions involving phenyl, cyclo-hexyl and dichloro-methane H-atom donors and perchlorate O-atom acceptors contribute to the stabilization of the crystal structure.

| S-EPMC3099967 | biostudies-literature

Dibromidobis[2-(dicyclo-hexyl-phosphan-yl)-biphenyl-?P]palladium(II).

Project description:The title compound, [PdBr(2)(C(24)H(31)P)(2)], has a distorted trans square-planar coordination of the Pd atom, which occupies an inversion centre. The most important bond distances include Pd-P of 2.380?(2)?Å and Pd-Br of 2.515?(2)?Å. Weak inter-molecular ?-? inter-actions between the benzene rings of adjacent mol-ecules [centroid-centroid distance = 3.949?(6)?Å] are present via crystallographic inversion centres, resulting in a one-dimensional supra-molecular architecture.

| S-EPMC2959319 | biostudies-literature

Tetra-bromidobis(dicyclo-hexyl-phosphane-?P)digallium(Ga-Ga).

Project description:The title compound, a Ga(II) dimer, [Ga(2)Br(4)(C(12)H(23)P)(2)], was synthesized by reaction of GaBr(THF)(n) (THF is tetra-hydro-furan) with dicyclo-hexyl-phosphine in toluene. At 150?K the crystallographically centrosymmetric molecule exhibits disorder in which one of the two independent cyclo-hexyl groups is modelled over two sites in a 62?(1):38?(1) ratio. In d(6)-benzene solution, the compound exhibits virtual C(2h) symmetry as determined by (1)H NMR. The coordination environment of the Ga(II) atom is distorted tetrahedral.

| S-EPMC3470134 | biostudies-literature

Acetonitrile-[2-(1-{bis-[2,4,6-tris-(trifluoro-meth-yl)phen-yl]phosphan-yloxy}-1-methyl-eth-yl)pyridine]-methyl-palladium(II) hexa-fluoridoanti-monate dichloro-methane hemisolvate.

Project description:In the title compound, [Pd(CH(3))(C(26)H(14)F(18)NOP)(C(2)H(3)N)][SbF(6)]·0.5CH(2)Cl(2), the Pd(2+) cation has a distorted square-planar environment, being coordinated by the acetonitrile [Pd-N = 2.078 (8) Å] and methyl [Pd-C = 2.052 (9) Å] groups and the bidentate ligand 2-(1-{bis-[2,4,6-tris-(trifluoro-meth-yl)phen-yl]phosphan-yloxy}-1-methyl-eth-yl)pyridine (L). In L, one -CF(3) group is rotationally disordered between two orientations in a 1:1 ratio. The solvent mol-ecule was treated as disordered between two positions related by an inversion center with occupancies fixed at 0.5. The crystal packing exhibits weak inter-molecular C-H⋯F contacts.

| S-EPMC3051981 | biostudies-literature

(Di-tert-butyl-phosphan-yl)bis-(diphenyl-phosphan-yl)phosphane.

Project description:The title phosphane, C(32)H(38)P(4) or (Ph(2)P)(2)P(P(t)Bu(2)), has a P atom that is linked to another three P atoms in a pyramidal configuration; the P-P distances in the range 2.2231?(7)-2.2446?(7)?Å indicate that the P-P bonds are single bonds.

| S-EPMC2961699 | biostudies-literature

{Bis[2-(diphenyl-phosphan-yl)eth-yl]phenyl-phosphane-κP,P',P''}[(Z)-8-mesityl-cyclo-oct-4-en-1-yl]platinum(II) tetra-fluorido-borate dichloro-methane disolvate.

Project description:In the title ionic compound, [Pt(C(17)H(23))(C(34)H(33)P(3))](BF(4))·2CH(2)Cl(2), the Pt(II) atom adopts a square-planar coordination geometry with the large (Z)-8-mesityl-cyclo-oct-4-en-1-yl group occupying the fourth coordination site. The (triphos)Pt moiety and the mesityl group are attached to the cyclo-oct-4-ene motif at the 1- and 8-position in a syn configuration. The (BF(4))(-) anion and one of the dichloromethane solvate molecules each are disordered over two sets of sites.

| S-EPMC3151910 | biostudies-literature

(?(6)-Benzene)-dichlorido(dicyclo-hexyl-phenyl-phosphane)ruthenium(II) benzene sesquisolvate.

Project description:The asymmetric unit of the title compound, [RuCl2(C6H6)(C18H27P)]·1.5C6H6, contains one mol-ecule of the Ru(II) complex and one and a half solvent molecules as one of these is located about a centre of inversion. The Ru(II) atom has a classical three-legged piano-stool environment being coordinated by an ?(6)-benzene ligand [Ru-centroid = 1.6964?(6)?Å], two chloride ligands with an average Ru-Cl bond length of 2.4138?(3)?Å and a dicyclo-hexyl-phenyl-phosphane ligand [Ru-P = 2.3786?(3)?Å]. The effective cone angle for the phosphane was calculated to be 158°. In the crystal, weak C-H?Cl hydrogen bonds link the Ru(II) complexes into centrosymmetric dimers. The crystal packing exhibits intra- and inter-molecular C-H?? inter-actions resulting in a zigzag pattern in the [101] direction.

| S-EPMC3588713 | biostudies-literature

Dicyclo-hex-yl(4-isopropyl-phen-yl)phosphane selenide.

Project description:In the title compund, C(21)H(33)PSe, the Se=P bond is part of a distorted tetra-hedral environment on the P atom. Both cyclo-hexyl groups adopt chair conformations. A cone angle of 170° was calculated using an adaptation of the Tolman model. Inter-molecular C-H?Se and C-H?Cg contacts are observed (Cg is the centroid of the benzene ring).

| S-EPMC3295440 | biostudies-literature

(?(6)-Benzene)-dichlorido-(chloro-dicyclo-hexyl-phosphane-?P)ruthenium(II) chloro-form monosolvate.

Project description:The title compound, [RuCl2(?(6)-C6H6)(C12H22ClP)]·CHCl3, was prepared by reaction of [RuCl2(?(6)-C6H6)]2 with chloro-dicyclo-hexyl-phosphane in CHCl3 at 323?K under argon. The Ru(II) atom is surrounded by one arene ligand, two Cl atoms and a phosphane ligand in a piano-stool geometry. The phosphane ligand is linked by the P atom, with an Ru-P bond length of 2.3247?(4)?Å. Both cyclo-hexyl rings at the P atom adopt a chair conformation. In the crystal, the Ru(II) complex mol-ecule and the chloro-form solvent mol-ecule are linked by a bifurcated C-H?(Cl,Cl) hydrogen bond. Intra-molecular C-H?Cl hydrogen bonds are also observed.

| S-EPMC4120624 | biostudies-literature

[1,1'-Bis(diphenyl-phosphan-yl)cobalto-cenium]carbonyl-chloridohydrido(triphenyl-phosphane)ruthenium(II) hexa-fluoridophosphate dichloro-methane disolvate.

Project description:In the title compound, [CoRu(C(17)H(14)P)(2)ClH(C(18)H(15)P)(CO)]PF(6)·2CH(2)Cl(2), the Ru(II) atom is coordinated by three P atoms from a chelating 1,1'-bis-(diphenyl-phosphan-yl)cobaltocenium ligand and a triphenyl-phosphine ligand, one CO ligand, one Cl atom and one H atom in a distorted octa-hedral geometry. In the cobaltocenium unit, the two cyclo-penta-dienyl rings are almost parallel, making a dihedral angle of 1.2?(3)°. The F atoms of the hexa-fluoridophosphate anion are disordered over two sets of sites, with an occupancy ratio of 0.849?(11):0.151?(11). Intra-molecular C-H?Cl hydrogen bonds occur in the complex cation. The complex cations, hexa-fluoridophosphate anions and dichloro-methane solvent mol-ecules are linked by inter-molecular C-H?F hydrogen bonds.

| S-EPMC3238603 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data