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1-(2,6-Dichloro-benzo-yl)-3-(3,5-dichloro-phen-yl)thio-urea.

ABSTRACT: The crystal structure of the title compound, C(14)H(8)Cl(4)N(2)OS, is composed of discrete mol-ecules with bond lengths and angles quite typical for thio-urea compounds of this class. The plane containing the central SONNCC atom set subtends a dihedral angle of 31.47?(3)° with the benzene ring. An intra-molecular N-H?O hydrogen bond stabilizes the mol-ecular conformation and the mol-ecules form centrosymmetric dimers via inter-molecular N-H?S hydrogen bonds.

SUBMITTER: Khawar Rauf M

PROVIDER: S-EPMC2968087 | biostudies-other | 2008

REPOSITORIES: biostudies-other

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1-(2,6-Dichloro-benzo-yl)-3-(3,5-dichloro-phen-yl)thio-urea.

Khawar Rauf M M Bolte Michael M Badshah Amin A

Acta crystallographica. Section E, Structure reports online 20081220 Pt 1

The crystal structure of the title compound, C(14)H(8)Cl(4)N(2)OS, is composed of discrete mol-ecules with bond lengths and angles quite typical for thio-urea compounds of this class. The plane containing the central SONNCC atom set subtends a dihedral angle of 31.47 (3)° with the benzene ring. An intra-molecular N-H⋯O hydrogen bond stabilizes the mol-ecular conformation and the mol-ecules form centrosymmetric dimers via inter-molecular N-H⋯S hydrogen bonds. ...[more]

PMID: 21581633

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1-(2,6-Dichloro-benzo-yl)-3-(3-methoxy-phen-yl)thio-urea.

Project description:The two aromatic rings in the title compound, C(15)H(12)Cl(2)N(2)O(2)S, enclose a dihedral angle of 37.49?(6)°. The mol-ecule exists in the solid state in its thione form with typical thio-urea C-S and C-O bonds lengths, as well as shortened C-N bonds. An intra-molecular N-H?O hydrogen bond stabilizes the mol-ecular conformation. In the crystal, mol-ecules are connected by N-H?O and N-H?S hydrogen bonds, forming chains running along the a axis.

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Project description:The title compound, C(14)H(9)Cl(3)N(2)OS, has bond lengths and angles which are quite typical for thio-urea compounds of this class. The mol-ecule exists in the solid state in its thione form with typical thio-urea C=S and C=O bond lengths, as well as shortened C-N bonds. An intra-molecular N-H?O hydrogen bond stabilizes the mol-ecular conformation. Inter-molecular N-H?S hydrogen bonds link the mol-ecules to form centrosymmetric dimers.

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N-(3,4-Dichloro-phen-yl)thio-urea.

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1-(3,5-Dinitro-benzo-yl)-3,3-dipropyl-thio-urea.

Project description:The title thio-urea derivative, C(14)H(18)N(4)O(5)S, features two substantial twists between its component fragments: the dihedral angle between the SN(2)C (thio-urea) and ONC(2) (amide) residues is 48.89?(7)° and that between the benzene ring and the amide residue is 30.27?(7)°. In the crystal, mol-ecules are linked by bifurcated N-H?(O,S) hydrogen bonds, generating [001] supra-molecular chains.

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3-Acetyl-1-(2,3-dichloro-phen-yl)thio-urea.

Project description:In the crystal structure of the title compound, C(9)H(8)Cl(2)N(2)OS, there are two mol-ecules in the asymmetric unit which are connected by a pair of N-H?S hydrogen bonds. An intra-molecular N-H?O hydrogen bond stabilizes the mol-ecular conformation of each molecule.

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