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LiHo(PO(3))(4).

ABSTRACT: Lithium holmium(III) polyphosphate(V), LiHo(PO(3))(4), belongs to the type I of polyphosphates with general formula ALn(PO(3))(4), where A is a monovalent cation and Ln is a trivalent rare earth cation. In the crystal structure, the polyphosphate chains spread along the b-axis direction, with a repeat period of four tetra-hedra and 2(1) inter-nal symmetry. The Li and Ho atoms are both located on twofold rotation axes and are surrounded by four and eight O atoms, leading to a distorted tetra-hedral and dodeca-hedral coordination, respectively. The HoO(8) polyhedra are isolated from each other, the closest Ho?Ho distance being 5.570?(1)?Å.

SUBMITTER: Ben Zarkouna E

PROVIDER: S-EPMC2968134 | biostudies-other | 2009

REPOSITORIES: biostudies-other

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LiHo(PO(3))(4).

Ben Zarkouna Emna E Driss Ahmed A Férid Mokhtar M

Acta crystallographica. Section E, Structure reports online 20090123 Pt 2

Lithium holmium(III) polyphosphate(V), LiHo(PO(3))(4), belongs to the type I of polyphosphates with general formula ALn(PO(3))(4), where A is a monovalent cation and Ln is a trivalent rare earth cation. In the crystal structure, the polyphosphate chains spread along the b-axis direction, with a repeat period of four tetra-hedra and 2(1) inter-nal symmetry. The Li and Ho atoms are both located on twofold rotation axes and are surrounded by four and eight O atoms, leading to a distorted tetra-hedr ...[more]

PMID: 21581738

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