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Poly[ethane-1,2-diammonium tetra-?-chlorido-cadmate(II)].


ABSTRACT: The framework of the title compound, {(NH(3)CH(2)CH(2)NH(3))[CdCl(4)]}(n), is built upon layers parallel to (100) made up from corner-sharing [CdCl(6)] octa-hedra. NH(3)CH(2)CH(2)NH(3) (2+) cations are situated between the layers and are linked to the layers via an N-H?Cl hydrogen-bonding network. The Cd atom is located on an inversion centre and the coordination environment is described as highly distorted octa-hedral.

SUBMITTER: Lamhamdi A 

PROVIDER: S-EPMC2968258 | biostudies-other | 2009

REPOSITORIES: biostudies-other

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Poly[ethane-1,2-diammonium tetra-μ-chlorido-cadmate(II)].

Lamhamdi Abdellatif A   Mejdoubi Elmiloud E   Fejfarová Karla K   Dušek Michal M   El Bali Brahim B  

Acta crystallographica. Section E, Structure reports online 20090123 Pt 2


The framework of the title compound, {(NH(3)CH(2)CH(2)NH(3))[CdCl(4)]}(n), is built upon layers parallel to (100) made up from corner-sharing [CdCl(6)] octa-hedra. NH(3)CH(2)CH(2)NH(3) (2+) cations are situated between the layers and are linked to the layers via an N-H⋯Cl hydrogen-bonding network. The Cd atom is located on an inversion centre and the coordination environment is described as highly distorted octa-hedral. ...[more]

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