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Trans-Bis(acetonitrile-?N)tetra-aqua-cobalt(II) tetra-chloridocobaltate(II).

ABSTRACT: In the title complex, [Co(CH(3)CN)(2)(H(2)O)(4)][CoCl(4)], the Co(II) ions are octa-hedrally coordinated in the cation, with trans-disposed acetonitrile ligands, and tetra-hedrally coordinated in the anion. An extensive network of O-H(water)?Cl hydrogen bonds between cations and anions connects the ions into a three-dimensional network. The Co-Cl distances correlate with the number of hydrogen bonds accepted by the Cl atoms.

SUBMITTER: Patroniak V

PROVIDER: S-EPMC2968350 | biostudies-other | 2009

REPOSITORIES: biostudies-other

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trans-Bis(acetonitrile-κN)tetra-aqua-cobalt(II) tetra-chloridocobaltate(II).

Patroniak Violetta V Kubicki Maciej M

Acta crystallographica. Section E, Structure reports online 20090110 Pt 2

In the title complex, [Co(CH(3)CN)(2)(H(2)O)(4)][CoCl(4)], the Co(II) ions are octa-hedrally coordinated in the cation, with trans-disposed acetonitrile ligands, and tetra-hedrally coordinated in the anion. An extensive network of O-H(water)⋯Cl hydrogen bonds between cations and anions connects the ions into a three-dimensional network. The Co-Cl distances correlate with the number of hydrogen bonds accepted by the Cl atoms. ...[more]

PMID: 21581780

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