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Bis(5-chloro-quinolin-8-olato-?N,O)bis-(propan-2-olato-?O)titanium(IV).

ABSTRACT: The Ti(IV) atom in the title compound, [Ti(C(9)H(5)ClNO)(2)(C(3)H(7)O)(2)], is chelated by the substituted quinolin-8-olate anions in a distorted octa-hedral geometry. The N-donor atoms are in a cis alignment as are the O atoms of the propan-2-olate groups; the O atoms of the quinolin-8-olate groups are trans to each other. One C atom of one propan-2-olate group is disordered over two positions with occupancies of 0.733?(8):0.267?(8).

SUBMITTER: Fazaeli Y

PROVIDER: S-EPMC2968443 | biostudies-other | 2009

REPOSITORIES: biostudies-other

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Bis(5-chloro-quinolin-8-olato-κN,O)bis-(propan-2-olato-κO)titanium(IV).

Fazaeli Yousef Y Najafi Ezzatollah E Amini Mostafa M MM Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20090213 Pt 3

The Ti(IV) atom in the title compound, [Ti(C(9)H(5)ClNO)(2)(C(3)H(7)O)(2)], is chelated by the substituted quinolin-8-olate anions in a distorted octa-hedral geometry. The N-donor atoms are in a cis alignment as are the O atoms of the propan-2-olate groups; the O atoms of the quinolin-8-olate groups are trans to each other. One C atom of one propan-2-olate group is disordered over two positions with occupancies of 0.733 (8):0.267 (8). ...[more]

PMID: 21582059

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