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Neoaustin: a meroterpene produced by Penicillium sp.


ABSTRACT: The title meroterpene neoaustin {systematic name: (1'S,2'R,3S,7'R,9'S,11'S,12'R)-11'-hydr-oxy-2,2,2',9',12'-penta-methyl-6',15'-dimethyl-ene-2,6-dihydro-13'-oxaspiro-[pyran-3,5'-tetra-cyclo-[7.5.1.0(1,11).0(2,7)]penta-deca-ne]-6,10',14'-trione}, C(25)H(30)O(6), comprises five rings, three six-membered and two five-membered. The absolute configuration was established based on [?(D)] = +166.91° (c 1.21, CH(2)Cl(2)). In the crystal, the mol-ecules are connected into a supra-molecular helical chain via O-H?O hydrogen bonds reinforced by C-H?O contacts.

SUBMITTER: Zukerman-Schpector J 

PROVIDER: S-EPMC2968484 | biostudies-other | 2009

REPOSITORIES: biostudies-other

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Neoaustin: a meroterpene produced by Penicillium sp.

Zukerman-Schpector Julio J   Maganhi Stella H SH   Fill Taicia Pacheco TP   Rodrigues-Fo Edson E   Caracelli Ignez I  

Acta crystallographica. Section E, Structure reports online 20090225 Pt 3


The title meroterpene neoaustin {systematic name: (1'S,2'R,3S,7'R,9'S,11'S,12'R)-11'-hydr-oxy-2,2,2',9',12'-penta-methyl-6',15'-dimethyl-ene-2,6-dihydro-13'-oxaspiro-[pyran-3,5'-tetra-cyclo-[7.5.1.0(1,11).0(2,7)]penta-deca-ne]-6,10',14'-trione}, C(25)H(30)O(6), comprises five rings, three six-membered and two five-membered. The absolute configuration was established based on [α(D)] = +166.91° (c 1.21, CH(2)Cl(2)). In the crystal, the mol-ecules are connected into a supra-molecular helical chain  ...[more]

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