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2-[(4-tert-Butyl-anilino)(phen-yl)meth-yl]cyclo-hexa-none.

ABSTRACT: In the mol-ecule of the title compound, C(23)H(29)NO, the cyclo-hexa-none ring has been distorted from the standard chair conformation by the ketone group such that part of the ring is almost flat. The remaining [(4-tert-butyl-anilino)(phen-yl)meth-yl] portion of the mol-ecule is in an equatorial position on the cyclo-hexa-none ring. The dihedral angle between the two benzene rings is 81.52?(8)°. In the crystal packing, mol-ecules are linked by N-H?O hydrogen bonds into infinite one-dimensional chains along the a axis and these chains are stacked down the c axis. The crystal structure is further stabilized by weak C-H?O and C-H?? inter-actions.

SUBMITTER: Fun HK 

PROVIDER: S-EPMC2968565 | biostudies-other | 2009

REPOSITORIES: biostudies-other

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2-[(4-tert-Butyl-anilino)(phen-yl)meth-yl]cyclo-hexa-none.

Fun Hoong-Kun HK   Chantrapromma Suchada S   Rai Sankappa S   Shetty Prakash P   Isloor Arun M AM  

Acta crystallographica. Section E, Structure reports online 20090218 Pt 3

In the mol-ecule of the title compound, C(23)H(29)NO, the cyclo-hexa-none ring has been distorted from the standard chair conformation by the ketone group such that part of the ring is almost flat. The remaining [(4-tert-butyl-anilino)(phen-yl)meth-yl] portion of the mol-ecule is in an equatorial position on the cyclo-hexa-none ring. The dihedral angle between the two benzene rings is 81.52 (8)°. In the crystal packing, mol-ecules are linked by N-H⋯O hydrogen bonds into infinite one-dimensional  ...[more]

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