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Dicyclo-hexyl[N-(3-meth-oxy-2-oxido-benzyl-idene)valinato-?O,N,O']tin(IV).

ABSTRACT: In the title compound, [Sn(C(6)H(11))(2)(C(13)H(15)NO(4))], the Sn atom is five-coordinate and adopts a distorted trigonal-bipyramidal SnNC(2)O(2) geometry with the O atoms in axial positions. The metal atom forms five- and six-membered chelate rings with the O,N,O'-tridentate ligand. The two cyclo-hexyl groups bound to the Sn atom adopt chair conformations, with the Sn-C bonds in equatorial positions and a mean Sn-C distance of 2.138?(3)?Å.

SUBMITTER: Yang HJ

PROVIDER: S-EPMC2968808 | biostudies-other | 2009

REPOSITORIES: biostudies-other

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Dicyclo-hexyl[N-(3-meth-oxy-2-oxido-benzyl-idene)valinato-κO,N,O']tin(IV).

Yang Hong-Jun HJ Dang Yan-Qiu YQ

Acta crystallographica. Section E, Structure reports online 20090314 Pt 4

In the title compound, [Sn(C(6)H(11))(2)(C(13)H(15)NO(4))], the Sn atom is five-coordinate and adopts a distorted trigonal-bipyramidal SnNC(2)O(2) geometry with the O atoms in axial positions. The metal atom forms five- and six-membered chelate rings with the O,N,O'-tridentate ligand. The two cyclo-hexyl groups bound to the Sn atom adopt chair conformations, with the Sn-C bonds in equatorial positions and a mean Sn-C distance of 2.138 (3) Å. ...[more]

PMID: 21582345

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