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(Benzohydrazidato-?N',O)-[2-(benzoyl-hydrazono-?N,O)propion-ato-?O]oxido-vanadium(V).

ABSTRACT: The V(V) atom in the title compound, [VO(C(7)H(7)N(2)O)(C(10)H(8)N(2)O(3))], is N,O-chelated by the benzohydrazidate anion and O,N,O'-chelated by the 2-(benzoyl-hydrazono)propionate dianion. The distorted octa-hedral trans-N(2)O(4) coordination geometry is completed by the vandadyl O atom. Mol-ecules are linked by N-H?O hydrogen bonds into a supra-molecular chain structure parallel to [010].

SUBMITTER: Wong HW 

PROVIDER: S-EPMC2968822 | biostudies-other | 2009

REPOSITORIES: biostudies-other

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(Benzohydrazidato-κN',O)-[2-(benzoyl-hydrazono-κN,O)propion-ato-κO]oxido-vanadium(V).

Wong Hon Wee HW   Lo Kong Mun KM   Ng Seik Weng SW  

Acta crystallographica. Section E, Structure reports online 20090325 Pt 4

The V(V) atom in the title compound, [VO(C(7)H(7)N(2)O)(C(10)H(8)N(2)O(3))], is N,O-chelated by the benzohydrazidate anion and O,N,O'-chelated by the 2-(benzoyl-hydrazono)propionate dianion. The distorted octa-hedral trans-N(2)O(4) coordination geometry is completed by the vandadyl O atom. Mol-ecules are linked by N-H⋯O hydrogen bonds into a supra-molecular chain structure parallel to [010]. ...[more]