Browse
Submit Data
Databases
API
Help

Dataset Information

7 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

{4-Bromo-2-[(2-morpholinoeth-yl)imino-meth-yl]phenolato}iodido(methanol)zinc(II).

ABSTRACT: The title compound, [Zn(C(13)H(16)BrN(2)O(2))I(CH(3)OH)], is a new mononuclear zinc(II) complex synthesized by the reaction of equimolar quanti-ties of 5-bromo-salicylaldehyde, 2-morpholinoethyl-amine and ZnI(2) in methanol. The Zn atom is four-coordinate in a distorted tetra-hedral geometry, binding to a phenolate O and an imine N atom of the Schiff base ligand, the O atom of a methanol mol-ecule and one I(-) anion. In the crystal structure, adjacent mol-ecules are linked through inter-molecular O-H?O hydrogen bonds, forming centrosymmetric dimers.

SUBMITTER: Han CL

PROVIDER: S-EPMC2968908 | biostudies-other | 2009

REPOSITORIES: biostudies-other

ACCESS DATA

Json Xml

Publications

{4-Bromo-2-[(2-morpholinoeth-yl)imino-meth-yl]phenolato}iodido(methanol)zinc(II).

Han Cheng-Li CL

Acta crystallographica. Section E, Structure reports online 20090319 Pt 4

The title compound, [Zn(C(13)H(16)BrN(2)O(2))I(CH(3)OH)], is a new mononuclear zinc(II) complex synthesized by the reaction of equimolar quanti-ties of 5-bromo-salicylaldehyde, 2-morpholinoethyl-amine and ZnI(2) in methanol. The Zn atom is four-coordinate in a distorted tetra-hedral geometry, binding to a phenolate O and an imine N atom of the Schiff base ligand, the O atom of a methanol mol-ecule and one I(-) anion. In the crystal structure, adjacent mol-ecules are linked through inter-molecula ...[more]

PMID: 21582360

Similar Datasets

(4-Chloro-2-{[(pyridin-2-ylmeth-yl)imino]-meth-yl}phenolato)iodido(methanol)zinc(II).

Project description:The title Schiff base zinc(II) complex, [Zn(C(13)H(10)ClN(2)O)I(CH(3)OH)], was synthesized by the reaction of 5-chloro-salicyl-aldehyde, 2-amino-methyl-pyridine and zinc iodide in methanol. The Zn(II) atom is five-coordinated by one phenolate O atom, one imine and one pyridine N atom of the Schiff base ligand, one methanol O atom and one I atom, forming a distorted square-pyramidal geometry, with the I atom at the apical site. The dihedral angle between the benzene and pyridine rings is 22.9?(2)°. In the crystal, centrosymmetrically related mol-ecules are linked through inter-molecular O-H?O hydrogen bonds, forming dimers.

| S-EPMC3052144 | biostudies-literature

{4-Bromo-2-[3-(diethyl-ammonio)propyl-imino-meth-yl]phenolato}diiodidozinc(II) methanol solvate.

Project description:In the title complex, [ZnI(2)(C(14)H(21)BrN(2)O)]·CH(3)OH, the asymmetric unit consists of a mononuclear zinc(II) complex mol-ecule and a methanol solvent mol-ecule. The compound was derived from the zwitterionic form of the Schiff base 4-bromo-2-[3-(diethyl-amino)propyl-imino-meth-yl]phenol. The Zn(II) atom is four-coordinated by the imine N and phenolate O atoms of the Schiff base ligand and by two iodide ions in a distorted tetra-hedral coordination. In the crystal structure, the methanol mol-ecules are linked to the Schiff base mol-ecules through N-H?O and O-H?O hydrogen bonds. One I atom is disordered over two positions in a 0.702?(19):0.298?(19) ratio.

| S-EPMC2971364 | biostudies-literature

Bis(?-6-meth-oxy-2-{[(3-oxidoprop-yl)imino]-meth-yl}phenolato)nickel(II) methanol monosolvate.

Project description:The mol-ecular structure of the title complex, [Ni2(C11H13NO3)2]·CH3OH, contains two Ni(II) atoms and two doubly deprotonated 6-meth-oxy-2-{[(3-oxidoprop-yl)imino]-meth-yl}phenolate ligands. The Ni(II) atoms are each four-coordinated in a distorted square-planar geometry by three O atoms and one N atom derived from the phenolate ligands. The solvent mol-ecule is linked to the complex mol-ecule by two O-H?O hydrogen bonds.

| S-EPMC3772446 | biostudies-literature

Bis[4-bromo-2-(cyclo-pentyl-imino-meth-yl)phenolato]copper(II).

Project description:The title compound, [Cu(C(12)H(13)BrNO)(2)], was prepared by the reaction of 5-bromo-salicylaldehyde, cyclo-pentyl-amine and copper(II) acetate in an ethanol solution. The Cu(II) atom lies on an inversion center and is four-coordinated in a square-planar geometry by two N and two O atoms from two 4-bromo-2-(cyclo-pentyl-imino-meth-yl)phenolate Schiff base ligands.

| S-EPMC2968514 | biostudies-literature

Bis[2-(cyclo-propyl-imino-meth-yl)-5-methoxy-phenolato]zinc(II).

Project description:In the title complex, [Zn(C(11)H(12)NO(2))(2)], the Zn(2+) ion (site symmetry 2) is coordinated by two N,O-bidentate Schiff base ligands, generating a tetra-hedral ZnO(2)N(2) geometry for the metal ion.

| S-EPMC2979218 | biostudies-literature

Bis{5-meth-oxy-2-[(1H-pyrrol-2-yl)methyl-imino-meth-yl]phenolato}zinc(II).

Project description:The title compound, [Zn(C(13)H(13)N(2)O(2))(2)], contains a Zn(II) centre, located on a twofold rotation axis, that is coordinated by two O atoms and two N atoms from two salicylal Schiff base mol-ecules. The crystal structure is stabilized by inter-molecular C-H?O hydrogen bonds.

| S-EPMC2970064 | biostudies-literature

Bis{2-[(2-furylmeth-yl)imino-meth-yl]-5-meth-oxy-phenolato-?N,O}zinc(II).

Project description:In the title complex, [Zn(C(13)H(12)NO(3))(2)], the Zn(II) ion is located on a twofold rotation axis and is coordinated by two bidentate Schiff base ligands in a distorted tetra-hedral environment. The complex mol-ecules are stacked in columns along the b axis through C-H?O hydrogen bonds.

| S-EPMC3099774 | biostudies-literature

Bis{4-bromo-2-[(naphthalen-1-yl-imino)-meth-yl]phenolato-?N,O}copper(II).

Project description:The title complex, [Cu(C(17)H(11)BrNO)(2)], lies on a centre of inversion. The chelating Schiff base anions define a square-planar N(2)O(2) donor set. The nearly perpendicular orientation of the naphthyl residues of the chelate ring [dihedral angle = 82.12?(12)°] precludes the Cu(II) centre from additional coordination. In the refinement, the naphthyl rings were found to be disordered over two positions.; the major component has a site occupancy of 0.667?(4).

| S-EPMC3297236 | biostudies-literature

Dibromido{2-[2-(piperidinium-1-yl)ethyl-imino-meth-yl]phenolato}zinc(II) monohydrate.

Project description:The asymmetric unit of the title compound, [ZnBr(2)(C(14)H(20)N(2)O)]·H(2)O, consists of a mononuclear Schiff base zinc(II) complex mol-ecule and a solvent water mol-ecule. The Zn(II) atom is four-coordinated in an approximately tetra-hedral geometry, binding to the imine N and phenolate O atoms of the neutral zwitterionic Schiff base ligand and to two terminal Br(-) anions. In the crystal structure, mol-ecules are linked through inter-molecular O-H?Br and O-H?O hydrogen bonds, forming chains running along the b axis.

| S-EPMC2961651 | biostudies-literature

Bis[(E)-4-bromo-2-(ethoxy-imino-meth-yl)phenolato-?N,O]copper(II).

Project description:The title compound, [Cu(C(9)H(9)BrNO(2))(2)], is a centrosymmetric mononuclear copper(II) complex. The Cu atom is four-coordinated in a trans-CuN(2)O(2) square-planar geometry by two phenolate O and two oxime N atoms from two symmetry-related N,O-bidentate (E)-4-bromo-2-(ethoxy-imino-meth-yl)phenolate oxime-type ligands. An inter-esting feature of the crystal structure is the centrosymmetric inter-molecular Cu?O inter-action [3.382?(1)?Å], which establishes an infinite chain structure along the b axis.

| S-EPMC2971190 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data