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(N-n-Butyl-pyridine-4-carbothio-amide-?N)chloridobis(dimethyl-glyoximato-?N,N')cobalt(III) hemihydrate.

ABSTRACT: The title compound, trans-[Co(C(4)H(7)N(2)O(2))(2)Cl(C(10)H(14)N(2)S)]·0.5H(2)O, contains two independent mol-ecules in the asymmetric unit in which the Co(III) ions are coordinated in slightly distorted octa-hedral coordination environments. The bis-chelating glyoximate ligands, which occupy equatorial sites, are linked by interligand O-H?O hydrogen bonds. The dihedral angles between the mean planes of the glyoximate ligands in each mol-ecule are 2.07?(8) and 1.60?(1)°. The asymmetric unit contains a solvent water mol-ecule which is disordered over two sites with refined occupancies 0.64?(2) and 0.36?(2).

SUBMITTER: Revathi C

PROVIDER: S-EPMC2969215 | biostudies-other | 2009

REPOSITORIES: biostudies-other

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(N-n-Butyl-pyridine-4-carbothio-amide-κN)chloridobis(dimethyl-glyoximato-κN,N')cobalt(III) hemihydrate.

Revathi C C Dayalan A A Sethusankar K K

Acta crystallographica. Section E, Structure reports online 20090620 Pt 7

The title compound, trans-[Co(C(4)H(7)N(2)O(2))(2)Cl(C(10)H(14)N(2)S)]·0.5H(2)O, contains two independent mol-ecules in the asymmetric unit in which the Co(III) ions are coordinated in slightly distorted octa-hedral coordination environments. The bis-chelating glyoximate ligands, which occupy equatorial sites, are linked by interligand O-H⋯O hydrogen bonds. The dihedral angles between the mean planes of the glyoximate ligands in each mol-ecule are 2.07 (8) and 1.60 (1)°. The asymmetric unit cont ...[more]

PMID: 21582722

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