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Dichloridobis(phenanthridine-?N)zinc(II).

ABSTRACT: In the mol-ecule of the title compound, [ZnCl(2)(C(13)H(9)N)(2)], the Zn(II) atom is four-coordinated in a distorted tetra-hedral configuration by two N atoms from two phenanthridine ligands and by two terminal Cl atoms. The dihedral angle between the planes of the phenanthridine ring systems is 69.92?(3)°. An intra-molecular C-H?Cl inter-action results in the formation of a planar five-membered ring, which is oriented at a dihedral angle of 8.32?(3)° with respect to the adjacent phenanthridine ring system. In the crystal structure, ?-? contacts between the phenanthridine systems [centroid-centroid distances = 3.839?(2), 3.617?(1) and 3.682?(1)?Å] may stabilize the structure. Two weak C-H?? inter-actions are also found.

SUBMITTER: Khoshtarkib Z

PROVIDER: S-EPMC2969295 | biostudies-other | 2009

REPOSITORIES: biostudies-other

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Dichloridobis(phenanthridine-κN)zinc(II).

Khoshtarkib Zeinab Z Ebadi Amin A Alizadeh Robabeh R Ahmadi Roya R Amani Vahid V

Acta crystallographica. Section E, Structure reports online 20090606 Pt 7

In the mol-ecule of the title compound, [ZnCl(2)(C(13)H(9)N)(2)], the Zn(II) atom is four-coordinated in a distorted tetra-hedral configuration by two N atoms from two phenanthridine ligands and by two terminal Cl atoms. The dihedral angle between the planes of the phenanthridine ring systems is 69.92 (3)°. An intra-molecular C-H⋯Cl inter-action results in the formation of a planar five-membered ring, which is oriented at a dihedral angle of 8.32 (3)° with respect to the adjacent phenanthridine ...[more]

PMID: 21582680

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