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Bis(6-meth-oxy-2-{[tris-(hydroxy-meth-yl)methyl-?O]imino-meth-yl}phenolato-?N,O)nickel(II) dihydrate.

ABSTRACT: In the title compound, [Ni(C(12)H(16)NO(5))(2)]·2H(2)O, the Ni(II) atom is coordinated by four O atoms and two N atoms from the two 6-meth-oxy-2-{[tris-(hydroxy-meth-yl)meth-yl]imino-meth-yl}phenolate ligands in a distorted octa-hedral coordination geometry. O-H?O hydrogen bonds link the complexes and uncoordinated water mol-ecules into two-dimensional networks parallel to (001).

SUBMITTER: Zhou T

PROVIDER: S-EPMC2969396 | biostudies-other | 2009

REPOSITORIES: biostudies-other

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Bis(6-meth-oxy-2-{[tris-(hydroxy-meth-yl)methyl-κO]imino-meth-yl}phenolato-κN,O)nickel(II) dihydrate.

Zhou Tian T Zhou Ru-Jin RJ An Zhe Z

Acta crystallographica. Section E, Structure reports online 20090617 Pt 7

In the title compound, [Ni(C(12)H(16)NO(5))(2)]·2H(2)O, the Ni(II) atom is coordinated by four O atoms and two N atoms from the two 6-meth-oxy-2-{[tris-(hydroxy-meth-yl)meth-yl]imino-meth-yl}phenolate ligands in a distorted octa-hedral coordination geometry. O-H⋯O hydrogen bonds link the complexes and uncoordinated water mol-ecules into two-dimensional networks parallel to (001). ...[more]

PMID: 21582708

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Bis(6-meth-oxy-2-{[tris-(hydroxy-meth-yl)-meth-yl]-imino-meth-yl}phenolato)-copper(II) dihydrate.

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Crystal structure of bis-{μ-2-meth-oxy-6-[(methyl-imino)-meth-yl]phenolato}bis-({2-meth-oxy-6-[(methyl-imino)-meth-yl]phenolato}nickel(II)) involving different coordination modes of the same Schiff base ligand.

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