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[5-Chloro-2-hydroxy-N'-(2-oxido-ben-zyl-idene)benzo-hy-dra-zidato]-pyridine-copper(II).

ABSTRACT: In the title complex, [Cu(C(14)H(9)ClN(2)O(3))(C(5)H(5)N)], the Cu(II) ion exhibits a distorted trans-CuN(2)O(2) square-planar geometry arising from the O,O,N-tridentate ligand and a pyridine mol-ecule. An intra-molecular O-H?N hydrogen bond occurs. In the crystal structure, weak inter-molecular C-H?? inter-actions generate a chain. The crystal studied was an inversion twin.

SUBMITTER: Li P

PROVIDER: S-EPMC2969500 | biostudies-other | 2009

REPOSITORIES: biostudies-other

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[5-Chloro-2-hydroxy-N'-(2-oxido-ben-zyl-idene)benzo-hy-dra-zidato]-pyridine-copper(II).

Li Piyong P Li Dacheng D Shi Xuefeng X

Acta crystallographica. Section E, Structure reports online 20090606 Pt 7

In the title complex, [Cu(C(14)H(9)ClN(2)O(3))(C(5)H(5)N)], the Cu(II) ion exhibits a distorted trans-CuN(2)O(2) square-planar geometry arising from the O,O,N-tridentate ligand and a pyridine mol-ecule. An intra-molecular O-H⋯N hydrogen bond occurs. In the crystal structure, weak inter-molecular C-H⋯π inter-actions generate a chain. The crystal studied was an inversion twin. ...[more]

PMID: 21582679

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